Advertisements
Advertisements
प्रश्न
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
Advertisements
उत्तर
Given: Current (I) = 5 A
Time (t) = 20 min = 20 × 60 = 1200 sec
Atomic weight of Ni = 58.70
The reaction takes place in the following manner:
\[\ce{Ni^{2+} + 2e- -> Ni}\]
Equivalent weight of Ni = \[\ce{\frac{Atomic weight}{Number of valence electrons}}\]
= \[\ce{\frac{58.70}{2}}\]
= 29.35
According to Faraday’s first law of electrolysis,
W = Z I t
= \[\ce{\frac{Equivalent weight}{96500} \times I \times t}\]
= \[\ce{\frac{29.35}{96500} \times 5 \times 1200}\]
= 1.825 g
APPEARS IN
संबंधित प्रश्न
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
Number of faradays of electricity required to liberate 12 g of hydrogen is:
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
How much charge is required for the following reduction?
1 mol of Cu2+ to Cu.
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Write any two uses of H2SO4
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
State second law of electrolysis
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.
Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is
When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.
On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?
(Given: Molar mass of Aluminium is 27 g mol−1.)
