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State Second Law of Electrolysis - Chemistry

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प्रश्न

State second law of electrolysis

State Faraday’s second law of electrolysis

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उत्तर

Second law : It states that when the same amount of electricity is passed through different cells containing different electrolytes and arranged in series, the amount of substances oxidized or reduced at the representive electrode are directly proportional to their chemical equavalent masses

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2012-2013 (October)

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संबंधित प्रश्न

96500 coulombs correspond to the charge on how many electrons?


Write any four applications of electrochemical series


How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?

(Given: Molar mass of Calcium is 40 g mol−1.)


Number of faradays of electricity required to liberate 12 g of hydrogen is:


If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?


Consider the reaction: \[\ce{Cr2O^{2-}_7 + 14H^+ + 6e^- -> 2Cr^{3+} + 7H2O}\]

What is the quantity of electricity in coulombs needed to reduce 1 mol of  \[\ce{Cr2O^{2-}_7}\]?


How much charge is required for the following reduction? 

1 mol of Cu2+ to Cu.


How much charge is required for the following reduction:

1 mol of \[\ce{MnO^-_4}\] to Mn2+?


A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?


Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?


On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]

(A) 1.0

(B) 13.5

(C) 0.50

(D) 0.75


Explain Faraday’s second law of electrolysis


 Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?


How much quantity of electricity in coulomb is required to deposit 1.346 × 10-3 kg of Ag in 3.5 minutes from AgNO3 solution?
( Given: Molar mass of Ag is 108 × 10-3 kg mol-1 )


According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.


What will happen during the electrolysis of aqueous solution of \[\ce{CuSO4}\] by using platinum electrodes?

(i) Copper will deposit at cathode.

(ii) Copper will deposit at anode.

(iii) Oxygen will be released at anode.

(iv) Copper will dissolve at anode.


Consider the figure and answer the following question.

Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?


Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is


When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.


The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.


What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).


Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.


Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.

Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.

Select the most appropriate answer from the options given below:


How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?

(Given: Molar mass of Aluminium is 27 g mol−1.)


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