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State Second Law of Electrolysis

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प्रश्न

State second law of electrolysis

State Faraday’s second law of electrolysis

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उत्तर

Second law : It states that when the same amount of electricity is passed through different cells containing different electrolytes and arranged in series, the amount of substances oxidized or reduced at the representive electrode are directly proportional to their chemical equavalent masses

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2012-2013 (October)

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संबंधित प्रश्न

On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be

  • 1
  • 2
  • 3
  • 4

The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -

  1. 2098
  2. 96500
  3. 193000
  4. 4196

96500 coulombs correspond to the charge on how many electrons?


Write any four applications of electrochemical series


Number of faradays of electricity required to liberate 12 g of hydrogen is:


Consider the reaction:

\[\ce{Cr2O^{2-}_7 + 14H+ + 6e- -> 2Cr^{3+} + 7H2O}\]

What is the quantity of electricity in coulombs needed to reduce 1 mol of  \[\ce{Cr2O^{2-}_7}\]?


A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?


Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?


Draw neat labelled diagram of electrolytic refining of blister copper


What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?

(A) 1 : 2

(B) 2 : 1

(C) 1 : 8

(D) 8 : 1


Explain Faraday’s second law of electrolysis


How much quantity of electricity in coulomb is required to deposit 1.346 × 10-3 kg of Ag in 3.5 minutes from AgNO3 solution?
( Given: Molar mass of Ag is 108 × 10-3 kg mol-1 )


Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)


According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.


In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?


What will happen during the electrolysis of aqueous solution of CuSO4 in the presence of Cu electrodes?

(i) Copper will deposit at cathode.

(ii) Copper will dissolve at anode.

(iii) Oxygen will be released at anode.

(iv) Copper will deposit at anode.


Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.


Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.

Reason: Formation of oxygen at anode requires overvoltage.


Consider the figure and answer the following question.

Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?


Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is


Given `1/a` = 0.5 CM–1, R = 50 ohm, N = 1.0 then equivalent conductance of electrolytic cell is


On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.


The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.


How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?

(Given: Molar mass of Aluminium is 27 g mol−1.)


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