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State Second Law of Electrolysis

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प्रश्न

State second law of electrolysis

State Faraday’s second law of electrolysis

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उत्तर

Second law : It states that when the same amount of electricity is passed through different cells containing different electrolytes and arranged in series, the amount of substances oxidized or reduced at the representive electrode are directly proportional to their chemical equavalent masses

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2012-2013 (October)

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संबंधित प्रश्न

96500 coulombs correspond to the charge on how many electrons?


How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?

(Given: Molar mass of Calcium is 40 g mol−1.)


Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:

Na+(aq) + e ⟶ Na (s) E0 =  2.71 V

H+(aq) + e ⟶ `1/2`  H2 (g) E0 = 0.00 V

On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?


How much charge is required for the following reduction?

1 mol of Al3+ to Al.


How much charge is required for the following reduction? 

1 mol of Cu2+ to Cu.


How much charge is required for the following reduction? 

1 mol of \[\ce{MnO^-_4}\] to Mn2+.


A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?


Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?


What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?

(A) 1 : 2

(B) 2 : 1

(C) 1 : 8

(D) 8 : 1


Explain Faraday’s second law of electrolysis


Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.


 Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :

On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?


In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?


Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.

Reason: Formation of oxygen at anode requires overvoltage.


Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is


When during electrolysis of a solution of AgNO3, 9650 coulombs of charge pass through the electroplating bath, the mass of silver deposited on the cathode will be ______.


Given `1/a` = 0.5 CM–1, R = 50 ohm, N = 1.0 then equivalent conductance of electrolytic cell is


On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.


The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.


Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.


On passing electricity through nitrobenzene solution, it is converted into azobenzene. The mass of azobenzene is ______ mg, if the same quantity of electricity produces oxygen just sufficient to burn 96 mg of fullerene (C60


Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.

Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.

Select the most appropriate answer from the options given below:


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