Advertisements
Advertisements
प्रश्न
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
विकल्प
Both assertion and reason are true and the reason is the correct explanation of assertion.
Both assertion and reason are true and the reason is not the correct explanation of assertion.
Assertion is true but the reason is false.
Both assertion and reason are false.
Assertion is false but reason is true.
Advertisements
उत्तर
Both assertion and reason are true and the reason is the correct explanation of assertion.
Explanation:
At the anode, the following oxidation reactions are possible.
\[\ce{Cl^{-} (aq) -> 1/2 Cl_{2}(g) + e^{-}; E = 1.36V}\]
\[\ce{2H2O(l) -> O2(g) + 4H^{-} (aq) + 4e^{-}; E = 1.23V}\]
Lower value of Ecell is perferenced but due to overvolatage chlorine is liberated at anode.
APPEARS IN
संबंधित प्रश्न
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -
- 2098
- 96500
- 193000
- 4196
96500 coulombs correspond to the charge on how many electrons?
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Suggest a list of metals that are extracted electrolytically.
Consider the reaction: \[\ce{Cr2O^{2-}_7 + 14H^+ + 6e^- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction:
1 mol of Al3+ to Al?
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?
Consider the figure and answer the following question.
Cell ‘A’ has ECell = 2V and Cell ‘B’ has ECell = 1.1V which of the two cells ‘A’ or ‘B’ will act as an electrolytic cell. Which electrode reactions will occur in this cell?
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?
(Given: Molar mass of Aluminium is 27 g mol−1.)
