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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.

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प्रश्न

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.

विकल्प

  • Mixture of and

MCQ
रिक्त स्थान भरें
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उत्तर

Mixture of and

Explanation:

Both ortho- and para- compounds are formed in different yields as depicted below:

('X' represents Cl in this case)

Even though the ortho- product is the major product.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १३७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q I. 20. | पृष्ठ १३७

संबंधित प्रश्न

Draw the structure of the major monohalo product in the following reaction:


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

o-Br-C6H4CH(CH3)CH2CH3


Identify the compound Y in the following reaction.


In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?

(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]

(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]

(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{OH}\phantom{..}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]

(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]


What should be the correct IUPAC name for diethylbromomethane?


Which of the carbon atoms present in the molecule given below are asymmetric?

\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
\phantom{}\ce{O}\phantom{......}\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{H}\phantom{}\\
\end{array}\]


Which of the following compounds can be classified as aryl halides?

(i) \[\ce{p-ClC6H4CH2CH(CH3)2}\]

(ii) \[\ce{p-CH3CHCl(C6H4)CH2CH3}\]

(iii) \[\ce{o-BrH2C - C6H4CH(CH3)CH2CH3}\]

(iv) \[\ce{C6H5 - Cl}\]


Which of the products will be major product in the reaction given below? Explain.

\[\ce{CH3CH = CH2 + HI -> \underset{(A)}{CH3CH2CH2I} + \underset{(B)}{CH3CHICH3}}\]


Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?


Which of the following belongs to the class of vinyl halides?


Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

CH3C(C2H5 )2CH2Br


Write the structure of the following organic halogen compound.

1,4-Dibromobut-2-ene


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3CH2C(CH3)2CH2I}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Which of the following are secondary bromides?


IUPAC name of \[\begin{array}{cc}
\phantom{}\ce{CH3}\phantom{..........}\ce{Br}\phantom{........}\\
\phantom{}|\phantom{................}|\phantom{.........}\\
\phantom{}\ce{CH3CHCH2CHCHCH2CH3}\phantom{}\\
\phantom{}|\phantom{..}\\
\phantom{..}\ce{CH3}\phantom{}
\end{array}\] is ______.


Ethylidene chloride is a/an ______.


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