मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.

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प्रश्न

The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.

पर्याय

  • Mixture of and

MCQ
रिकाम्या जागा भरा
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उत्तर

Mixture of and

Explanation:

Both ortho- and para- compounds are formed in different yields as depicted below:

('X' represents Cl in this case)

Even though the ortho- product is the major product.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १३७]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q I. 20. | पृष्ठ १३७

संबंधित प्रश्‍न

Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH2CH(CH3)CH(C2H5)Cl


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH(CH3)CH(Br)CH3


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3C(Cl)(C2H5)CH2CH3


Draw the structure of major monohalo product in each of the following reactions :


Ethylidene chloride is a/an ______.


Haloalkanes contain halogen atom (s) attached to the sp3 hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.

(i) 2-Bromopentane

(ii) Vinyl chloride (chloroethene)

(iii) 2-chloroacetophenone

(iv) Trichloromethane


Which of the products will be major product in the reaction given below? Explain.

\[\ce{CH3CH = CH2 + HI -> \underset{(A)}{CH3CH2CH2I} + \underset{(B)}{CH3CHICH3}}\]


Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?


Match the structures of compounds given in Column I with the classes of compounds given in Column II.

  Column I Column II
(i) \[\begin{array}{cc}
\ce{CH3 - CH - CH3}\\
|\phantom{..}\\
\ce{X}\phantom{..}
\end{array}\]
(a) Aryl halide
(ii) \[\ce{CH2 = CH - CH2 - X}\] (b) Alkyl halide
(iii) (c) Vinyl halide
(iv) \[\ce{CH2 = CH - X}\] (d) Allyl halide

Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides?


Name the following halide according to IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH2CH2C(CH3)2CH2I}\]


Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH2C(CH3)2CH2I


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides. 

\[\ce{CH3CH2C(CH3)2CH2I}\]


Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:  

\[\ce{CH3CH2C(CH3)2CH2I}\] 


Which of the following are secondary bromides?


IUPAC name of is ______.


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