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प्रश्न
Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?
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उत्तर
Aryl halides can't be prepared by reaction of phenol with \[\ce{HCl}\] in presence of \[\ce{ZnCl2}\] because the carbon-oxygen bond in phenols has partial double bond character and it, being stronger than a single bond, is difficult to break.
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संबंधित प्रश्न
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH2C(CH3)2CH2I
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH = CHC(Br)(CH3)2
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
m-ClCH2C6H4CH2C(CH3)3
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzoyl (primary, secondary, tertiary), vinyl or aryl halide:
o-Br-C6H4CH(CH3)CH2CH3
When two halogen atoms are attached to the same carbon atom then it is:
In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?
(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]
(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{OH}\phantom{..}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]
The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.
Haloalkanes contain halogen atom (s) attached to the sp3 hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.
(i) 2-Bromopentane
(ii) Vinyl chloride (chloroethene)
(iii) 2-chloroacetophenone
(iv) Trichloromethane
Classify the following compound as a primary, secondary and tertiary halide.
2-Bromo-2-methylpropane
Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides?
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3CH2C(CH3)2CH2I}\]
Name the following halide according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl, or aryl halide:
\[\ce{CH3CH2C(CH3)2CH2I}\]
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3CH2 C(CH3)2CH2I}\]
Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Write the structure of the following organic halogen compound.
1,4-Dibromobut-2-ene
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
\[\ce{CH3C(C2H5)2CH2Br}\]
Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
\[\ce{CH3C(C2H5)2CH2Br}\]
Write the structure of the following organic halogen compound.
4-tert-Butyl-3-iodoheptane
What should be the correct IUPAC name for diethylbromomethane?
