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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Why can aryl halides not be prepared by reaction of phenol with HCl in the presence of ZnClX2?

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प्रश्न

Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?

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उत्तर

Aryl halides can't be prepared by reaction of phenol with \[\ce{HCl}\] in presence of \[\ce{ZnCl2}\] because the carbon-oxygen bond in phenols has partial double bond character and it, being stronger than a single bond, is difficult to break.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४४]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q III. 63. | पृष्ठ १४४

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