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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Why can aryl halides not be prepared by reaction of phenol with HCl in the presence of ZnClX2?

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प्रश्न

Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?

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उत्तर

Aryl halides can't be prepared by reaction of phenol with \[\ce{HCl}\] in presence of \[\ce{ZnCl2}\] because the carbon-oxygen bond in phenols has partial double bond character and it, being stronger than a single bond, is difficult to break.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४४]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q III. 63. | पृष्ठ १४४

संबंधित प्रश्‍न

Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH(CH3)CH(Br)CH3


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH = CHC(Br)(CH3)2


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

p-ClC6H4CH2CH(CH3)2


When two halogen atoms are attached to the same carbon atom then it is:


Identify the compound Y in the following reaction.


Which is the correct IUPAC name for \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - Br}\\
\phantom{}|\phantom{.......}\\
\phantom{}\ce{C2H5}\phantom{....}
\end{array}\]?


What should be the correct IUPAC name for diethylbromomethane?


Which of the products will be major product in the reaction given below? Explain.

\[\ce{CH3CH = CH2 + HI -> \underset{(A)}{CH3CH2CH2I} + \underset{(B)}{CH3CHICH3}}\]


Classify the following compound as a primary, secondary and tertiary halide.

2-Bromo-2-methylpropane


Which of the following belongs to the class of vinyl halides?


Name the following halide according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl, or aryl halide:

\[\ce{CH3CH2C(CH3)2CH2I}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3CH2 C(CH3)2CH2I}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]


Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides: 

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


The IUPAC name of the compound shown below is:


The given compound

 

is an example of__________.


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