मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Identify the compound Y in the following reaction. →273−278KNANOX2+HCl →CuX2 ClY+NX2

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प्रश्न

Identify the compound Y in the following reaction.

पर्याय

MCQ
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उत्तर

Explanation:

When a primary aromatic amine, dissolved or suspended in cold aqueous mineral acid and treated with sodium nitrite, a diazonium salt is formed. When this freshly prepared diazonium salt is mixed with cuprous chloride, diazonium group is replaced by −Cl.

Then chlorobenzene is formed which is Y in this reaction.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १३४]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q I. 3. | पृष्ठ १३४

संबंधित प्रश्‍न

Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

(CH3)2CHCH(Cl)CH3


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH2CH(CH3)CH(C2H5)Cl


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

(CH3)3CCH2CH(Br)C6H5


Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3CH = C(Cl)CH2CH(CH3)2


Haloalkanes contain halogen atom (s) attached to the sp3 hybridised carbon atom of an alkyl group. Identify haloalkane from the following compounds.

(i) 2-Bromopentane

(ii) Vinyl chloride (chloroethene)

(iii) 2-chloroacetophenone

(iv) Trichloromethane


Match the items of Column I and Column II.

  Column I Column II
(i) SN1 reaction (a) vic-dibromides
(ii) Chemicals in fire extinguisher (b) gem-dihalides
(iii) Bromination of alkenes (c) Racemisation
(iv) Alkylidene halides (d) Saytzeff rule
(v) Elimination of HX from alkylhalide (e) Chlorobromocarbons

Match the structures of compounds given in Column I with the classes of compounds given in Column II.

  Column I Column II
(i) \[\begin{array}{cc}
\ce{CH3 - CH - CH3}\\
|\phantom{..}\\
\ce{X}\phantom{..}
\end{array}\]
(a) Aryl halide
(ii) \[\ce{CH2 = CH - CH2 - X}\] (b) Alkyl halide
(iii) (c) Vinyl halide
(iv) \[\ce{CH2 = CH - X}\] (d) Allyl halide

Which alkyl halide has maximum density


Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides?


Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

CH3C(Cl)(C2H5)CH2CH3


Name the following halide according to the IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH_3CH_2C(CH_3)_2CH_2I}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH3C(CI)(C2H5)CH2CH3}\]


Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Draw the structure of the major monohalo product in the following reaction:


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Ethylidene chloride is a/an ______.


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