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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Identify the compound Y in the following reaction. →273−278KNANOX2+HCl →CuX2 ClY+NX2 - Chemistry

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प्रश्न

Identify the compound Y in the following reaction.

विकल्प

MCQ
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उत्तर

Explanation:

When a primary aromatic amine, dissolved or suspended in cold aqueous mineral acid and treated with sodium nitrite, a diazonium salt is formed. When this freshly prepared diazonium salt is mixed with cuprous chloride, diazonium group is replaced by −Cl.

Then chlorobenzene is formed which is Y in this reaction.

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अध्याय 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १३४]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 10 Haloalkanes and Haloarenes
Exercises | Q I. 3. | पृष्ठ १३४

संबंधित प्रश्न

Draw the structure of major monohalo products in the following reaction:


When two halogen atoms are attached to the same carbon atom then it is:


In which of the following molecules carbon atom marked with asterisk (*) is asymmetric?

(a) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]

(b) \[\begin{array}{cc}
\ce{D}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{.}\ce{I}\phantom{...}\ce{Br}\phantom{..}\ce{Cl}
\end{array}\]

(c) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{OH}\phantom{..}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]

(d) \[\begin{array}{cc}
\ce{H}\\
|\\
\phantom{.}\ce{C^*}\phantom{}\\
\phantom{}/\phantom{..}|\phantom{..}\backslash\phantom{}\\
\phantom{..}\ce{H}\phantom{...}\ce{C2H5}\phantom{}\ce{CH3}
\end{array}\]


The position of \[\ce{-Br}\] in the compound in \[\ce{CH3CH = CH(Br)(CH3)2}\] can be classified as ______.


Which is the correct IUPAC name for \[\begin{array}{cc}
\ce{CH3 - CH - CH2 - Br}\\
\phantom{}|\phantom{.......}\\
\phantom{}\ce{C2H5}\phantom{....}
\end{array}\]?


The reaction of toluene with chlorine in the presence of iron and in the absence of light yields ______.


Which of the carbon atoms present in the molecule given below are asymmetric?

\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
\phantom{}\ce{O}\phantom{......}\ce{H}\phantom{...}\ce{OH}\phantom{...}\ce{H}\phantom{}\\
\end{array}\]


Which of the following compounds can be classified as aryl halides?

(i) \[\ce{p-ClC6H4CH2CH(CH3)2}\]

(ii) \[\ce{p-CH3CHCl(C6H4)CH2CH3}\]

(iii) \[\ce{o-BrH2C - C6H4CH(CH3)CH2CH3}\]

(iv) \[\ce{C6H5 - Cl}\]


Why can aryl halides not be prepared by reaction of phenol with \[\ce{HCl}\] in the presence of \[\ce{ZnCl2}\]?


Two isomers (A) and (B) with molar mass 184 g/mol and elemental composition C 52.2%; H 4.9% and Br 42.9% gave benzoic acid and p-bromobenzoic acid, respectively on oxidation with KMnO4. Isomer ‘A’ is optically active and gives a pale yellow precipitate when warmed with alcoholic AgNO3. Isomer ‘A’ and ‘B’ are, respectively:


Which of the following belongs to the class of vinyl halides?


Name the following halide according to IUPAC system and classify it as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(C2H5)2CH2Br}\]


Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

CH3C(C2H5 )2CH2Br


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:

\[\ce{CH3C(Cl)(C2H5)CH2CH3}\]


Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH3C(C2H5)2CH2Br}\]


Give the IUPAC name of the compound.

\[\ce{CICH2 C ≡ CCH2 Br}\]


Name the following halide according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides. 

\[\ce{CH3CH2C(CH3)2CH2I}\]


Name the following halide according to IUPAC system and classify as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:

\[\ce{CH3C(C2H5)2CH2Br}\]


IUPAC name of \[\begin{array}{cc}
\phantom{}\ce{CH3}\phantom{..........}\ce{Br}\phantom{........}\\
\phantom{}|\phantom{................}|\phantom{.........}\\
\phantom{}\ce{CH3CHCH2CHCHCH2CH3}\phantom{}\\
\phantom{}|\phantom{..}\\
\phantom{..}\ce{CH3}\phantom{}
\end{array}\] is ______.


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