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प्रश्न
Predict the possible product of the following reaction.
sulphonation of chlorobenzene
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उत्तर
Chloro group is ortho and para directing group. So, sulphonation of chlorobenzene gives p-chlorobenzene sulphonic acid and o- chlorobenzene sulphonic acid.
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\[\begin{array}{cc}
\phantom{.............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}\\
\end{array}\]
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\[\begin{array}{cc}
\phantom{..............................}\ce{CH3}\\
\phantom{...........................}|\\
\ce{CH3 - C = CH2 + HBr ->[benzoyl][peroxide] CH3 - CH - CH2Br}\\
|\phantom{....................................}\\
\ce{CH3}\phantom{.................................}
\end{array}\]
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- State the rule that governs the formation of this product.
