Advertisements
Advertisements
प्रश्न
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Advertisements
उत्तर
AlCl3 
Al+3 + 3Cl-
Al+3 + 3e- Al
1 mole of Al requires passage of 3 moles of electrons. The charge on 3 moles of e- is 3 Faraday.
Moles of Al produced = `"mass of Al"/"molar mass of Al"`
= `13/27`
= 0.48 moles
As 3F of electricity produces 1 mole of Al
∴ No. of faradays of electricity required to produce 0.48 mole of Al
= 0.48 x 3
= 1.44 Faraday
APPEARS IN
संबंधित प्रश्न
On calculating the strength of current in amperes if a charge of 840C (coulomb) passes through an electrolyte in 7 minutes, it will be
- 1
- 2
- 3
- 4
96500 coulombs correspond to the charge on how many electrons?
Write any four applications of electrochemical series
Number of faradays of electricity required to liberate 12 g of hydrogen is:
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Suggest a list of metals that are extracted electrolytically.
Consider the reaction:
\[\ce{Cr2O^{2-}_7 + 14H+ + 6e- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction?
1 mol of \[\ce{MnO^-_4}\] to Mn2+.
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively, are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
What is the ratio of volumes of H2 and O2 liberated during electrolysis of acidified water?
(A) 1 : 2
(B) 2 : 1
(C) 1 : 8
(D) 8 : 1
Explain Faraday’s second law of electrolysis
Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
Solve the following question.
A steady current of 2 amperes was passed through two electrolytic cells X and Y connected in series containing electrolytes FeSO4 and ZnSO4 until 2.8 g of Fe deposited at the cathode of cell X. How long did the current flow? Calculate the mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = 56 g mol–1, Zn = 65.3 g mol–1, 1F = 96500 C mol–1)
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?
What will happen during the electrolysis of aqueous solution of \[\ce{CuSO4}\] by using platinum electrodes?
(i) Copper will deposit at cathode.
(ii) Copper will deposit at anode.
(iii) Oxygen will be released at anode.
(iv) Copper will dissolve at anode.
Aqueous copper sulphate solution and aqueous silver nitrate solution are electrolysed by 1 ampere current for 10 minutes in separate electrolytic cells. Will the mass of copper and silver deposited on the cathode be same or different? Explain your answer.
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
Time Required to deposite one millimole of aluminium metal by the passage of 9.65 ampere through aqueous solution of aluminium is
Given `1/a` = 0.5 CM–1, R = 50 ohm, N = 1.0 then equivalent conductance of electrolytic cell is
On electrolysis of dilute sulphuric acid using platinum electrodes, the product obtained at the anode will be ______.
The quantity of electricity needed to separately electrolyse 1 M solution of ZnSO4, AlCl3, and AgNO3 completely is in the ratio of ______.
Through an aqueous solution of an unknown salt of metal M (M = 200 g/mol) a current of 1.93 A is passed for 50 min. If 4 g of metal is produced at cathode. The charge on metal ion in solution is ______.
Assertion (A): During electrolysis of aqueous copper sulphate solution using copper electrodes hydrogen gas is released at the cathode.
Reason (R): The electrode potential of Cu2+/Cu is greater than that of H+/H2.
Select the most appropriate answer from the options given below:
