Advertisements
Advertisements
Question
How many faradays of electricity are required to produce 13 gram of aluminium from aluminium chloride solution? (Given: Molar mass of Al = 27.0-gram mol–1)
Advertisements
Solution
AlCl3 
Al+3 + 3Cl-
Al+3 + 3e- Al
1 mole of Al requires passage of 3 moles of electrons. The charge on 3 moles of e- is 3 Faraday.
Moles of Al produced = `"mass of Al"/"molar mass of Al"`
= `13/27`
= 0.48 moles
As 3F of electricity produces 1 mole of Al
∴ No. of faradays of electricity required to produce 0.48 mole of Al
= 0.48 x 3
= 1.44 Faraday
APPEARS IN
RELATED QUESTIONS
The charge of how many coulomb is required to deposit 1.0 g of sodium metal (molar mass 23.0 g mol-1) from sodium ions is -
- 2098
- 96500
- 193000
- 4196
96500 coulombs correspond to the charge on how many electrons?
Write any four applications of electrochemical series
How much electricity in terms of Faraday is required to produce 20 g of Ca from molten CaCl2?
(Given: Molar mass of Calcium is 40 g mol−1.)
Using the E° values of A and B, predict which is better for coating the surface of iron [E°(Fe+2/Fe) = -0.44V] to prevent corrosion and why?
Given: E° (A+2/A)=-2.37 V: E°(B+2/B)= -0.14V
Following reactions occur at cathode during the electrolysis of aqueous sodium chloride solution:
Na+(aq) + e− ⟶ Na (s) E0 = 2.71 V
H+(aq) + e− ⟶ `1/2` H2 (g) E0 = 0.00 V
On the basis of their standard reduction electrode potential (E0) values, which reaction is feasible at the cathode and why?
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Suggest a list of metals that are extracted electrolytically.
Consider the reaction:
\[\ce{Cr2O^{2-}_7 + 14H+ + 6e- -> 2Cr^{3+} + 7H2O}\]
What is the quantity of electricity in coulombs needed to reduce 1 mol of \[\ce{Cr2O^{2-}_7}\]?
How much charge is required for the following reduction?
1 mol of Al3+ to Al.
How much charge is required for the following reduction?
1 mol of Cu2+ to Cu.
On passing 1.5 F charge, the number of moles of aluminium deposited at cathode are _______ [Molar mass of Al = 27 gram mol–1]
(A) 1.0
(B) 13.5
(C) 0.50
(D) 0.75
Write any two uses of H2SO4
Draw neat labelled diagram of electrolytic refining of blister copper
Explain Faraday’s second law of electrolysis
Calculate the mass of Ag deposited at cathode when a current of 2 amperes was passed through a solution of AgNO3 for 15 minutes.
(Given : Molar mass of Ag = 108 g mol−1 lF = 96500 C mol−1)
Write the name of the cell which is generally used in transistors. Write the reactions taking place at the anode and the cathode of this cell.
Following reactions occur at cathode during the electrolysis of aqueous copper(II) chloride solution :
On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why ?
How much quantity of electricity in coulomb is required to deposit 1.346 × 10-3 kg of Ag in 3.5 minutes from AgNO3 solution?
( Given: Molar mass of Ag is 108 × 10-3 kg mol-1 )
According to Faraday’s First Law of Electrolysis, the amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the ____________.
In the electrolysis of aqueous sodium chloride solution which of the half cell reaction will occur at anode?
Assertion: Electrolysis of NaCl solution gives chlorine at anode instead of O2.
Reason: Formation of oxygen at anode requires overvoltage.
What is the quantity of electricity in Coulombs required to produce 4.8 g of Mg from molten MgCl2? How much Ca will be produced if the same amount of electricity was passed through molten CaCl2? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).
A current of 4 amp was passed for 2 hours through a solution of copper sulphate when 5.0 g of copper was deposited. The current efficiency is ______% (Cu = 63.5).
How much electricity in terms of Faraday is required to produce 40.0 g of Al from molten Al2O3?
(Given: Molar mass of Aluminium is 27 g mol−1.)
