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Karnataka Board PUCPUC Science 2nd PUC Class 12

PUC Science 2nd PUC Class 12 - Karnataka Board PUC Question Bank Solutions for Chemistry

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Chemistry
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Define limiting molar conductivity.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Why conductivity of an electrolyte solution decreases with the decrease in concentration ?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Write the mechanism of the following reaction :

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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The conductivity of 0.20 mol L−1 solution of KCl is 2.48 × 10−2 S cm−1. Calculate its molar conductivity and degree of dissociation (α). Given λ0 (K+) = 73.5 S cm2 mol−1 and λ0 (C1) = 76.5 S cm2 mol−1.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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What is the basicity of H3PO3 ?

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Why does the conductivity of a solution decrease with dilution?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Complete the following equations : P4 + H2O →

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Write the mechanism of the following reaction :

[7] Alcohols, Phenols and Ethers
Chapter: [7] Alcohols, Phenols and Ethers
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Give reasons for the following : H3PO2 is a stronger reducing agent than H3PO3.

 

[7] P - Block Elements
Chapter: [7] P - Block Elements
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Write the chemical equations to illustrate the following name reaction: 

Cannizzaro’s reaction

[8] Aldehydes, Ketones and Carboxylic Acids
Chapter: [8] Aldehydes, Ketones and Carboxylic Acids
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Define the following terms: Molar conductivity (m)

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Calculate the efficiency of packing in case of a metal crystal for body-centred cubic

[1] Solid State
Chapter: [1] Solid State
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Niobium crystallises in body-centred cubic structure. If density is 8.55 g cm−3, calculate atomic radius of niobium using its atomic mass 93 u.

[1] Solid State
Chapter: [1] Solid State
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The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation and dissociation constant. Given \[\ce{λ^0_{(H^+)}}\] = 349.6 S cm2 mol1 and \[\ce{λ^0_{(HCOO^-)}}\] = 54.6 S cm2 mol1.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:

Concentration/M 0.001 0.010 0.020 0.050 0.100
102 × κ/S m−1 1.237 11.85 23.15 55.53 106.74

Calculate ∧m for all concentrations and draw a plot between ∧m and c1/2. Find the value of `Lambda_m^0`.

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Conductivity of 0.00241 M acetic acid is 7.896 × 10−5 S cm−1. Calculate its molar conductivity and if `Lambda_m^0` for acetic acid is 390.5 S cm2 mol−1, what is its dissociation constant?

[2] Electrochemistry
Chapter: [2] Electrochemistry
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Describe some features of catalysis by zeolites.

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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What is shape selective catalysis?

[5] Surface Chemistry
Chapter: [5] Surface Chemistry
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Copper can be extracted by hydrometallurgy but not zinc. Explain.

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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What is the role of cryolite in the metallurgy of aluminium?

[6] General Principles and Processes of Isolation of Elements
Chapter: [6] General Principles and Processes of Isolation of Elements
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