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Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane and explain.
Cyclohexane, KCl, CH3OH, CH3CN
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Identify that the following compound is insoluble, partially soluble or highly soluble in water:
pentanol
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Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. Calculate the solubility of methane in benzene at 298 K under 760 mm Hg.
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The air is a mixture of a number of gases. The major components are oxygen and nitrogen with approximate proportion of 20% is to 79% by volume at 298 K. The water is in equilibrium with air at a pressure of 10 atm. At 298 K if the Henry’s law constants for oxygen and nitrogen are 3.30 × 107 mm and 6.51 × 107 mm respectively, calculate the composition of these gases in water.
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Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
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Calculate the emf of the cell in which the following reaction takes place:
\[\ce{Ni_{(s)} + 2Ag^+ (0.002 M) -> Ni^{2+} (0.160 M) + 2Ag_{(s)}}\]
Given that \[\ce{E^Θ_{cell}}\] = 1.05 V
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What is the significance of leaching in the extraction of aluminium?
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How can you separate alumina from silica in a bauxite ore associated with silica? Give equations, if any.
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How is leaching carried out in case of low grade copper ores?
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What are the different oxidation states exhibited by the lanthanoids?
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Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
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Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.
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The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
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Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.
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Write the electronic configurations of the element with the atomic number 61.
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Write the IUPAC name of the following coordination compound:
[Co(NH3)6]Cl3
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Write the IUPAC name of the following coordination compound:
[Co(NH3)5Cl]Cl2
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Write the IUPAC name of the following coordination compound:
K2[PdCl4]
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