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Question
Write the structures of A, B and C in the following:

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Solution

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\[\ce{CH3CH2CH2OH + SOCl2 ->}\]
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AgCN reacts with haloalkanes to form isocyanide. Haloalkanes react with KCN to form alkyl cyanides as the main product. Why?
Which of the following pairs is/are correctly matched?
| Reaction | Product | |
| I | RX + AgCN | RNC |
| II | RX + KCN | RCN |
| III | RX + KNO2 | \[\begin{array}{cc} \phantom{.......}\ce{O}\\ \phantom{.....}/\\ \ce{R - N}\phantom{....}\\ \phantom{.....}\backslash\backslash\\ \phantom{.......}\ce{O} \end{array}\] |
| IV | RX + AgNO2 | \[\ce{R-O-N=O}\] |
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Racemisation occurs in ______.
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Reason (R) : Bond enthalpy of C-I bond is less than that of C-Cl bond.
