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The vapour pressure of water is 12.3 kPa at 300 K. Calculate vapour pressure of 1 molal solution of a non-volatile solute in it.
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Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.
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A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:
- molar mass of the solute.
- vapour pressure of water at 298 K.
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100 g of liquid A (molar mass 140 g mol−1) was dissolved in 1000 g of liquid B (molar mass 180 g mol−1). The vapour pressure of pure liquid B was found to be 500 torr. Calculate the vapour pressure of pure liquid A and its vapour pressure in the solution if the total vapour pressure of the solution is 475 Torr.
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Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80 g of benzene is mixed with 100 g of toluene.
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What do you mean by activity and selectivity of catalysts?
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Why is zinc not extracted from zinc oxide through reduction using CO?
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The value of ΔtGθ for formation of Cr2O3 is −540 kJ mol−1 and that of Al2O3 is −827 kJ mol−1. Is the reduction of Cr2O3 possible with Al?
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Predict conditions under which Al might be expected to reduce MgO.
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Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
K[Cr(H2O)2(C2O4)2]
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Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(en)3]Cl3
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Indicate the types of isomerism exhibited by the following complex and draw the structures for these isomers:
[Co(NH3)5(NO2)](NO3)2
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Indicate the types of isomerism exhibited by the following complex and draw the structure for this isomer:
[Pt(NH3)(H2O)Cl2]
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How many geometrical isomers are possible in the following coordination entity?
[Cr(C2O4)3]3−
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How many geometrical isomers are possible in the following coordination entity?
[Co(NH3)3Cl3]
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Draw the structure of optical isomers of [Cr(C2O4)3]3−.
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Draw the structure of optical isomers of [PtCl2(en)2]2+.
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Draw the structure of optical isomers of [Cr(NH3)2Cl2(en)]+.
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Draw all the isomers (geometrical and optical) of [CoCl2(en)2]+.
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Draw all the isomers (geometrical and optical) of [Co(NH3)Cl(en)2]2+.
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