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Draw Newman and Sawhorse projections for the eclipsed and staggered conformations of ethane. Which of these conformations is more stable and why?
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If the density of a solution is 3.12 g mL–1, the mass of 1.5 mL solution in significant figures is ______.
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Write the general outer electronic configuration of d- block elements.
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Which of the following are isoelectronic species i.e., those having the same number of electrons?
Na+, K+, Mg2+, Ca2+, S2–, Ar
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What are the atomic numbers of elements whose outermost electrons is represented by 3s1.
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What are the atomic numbers of elements whose outermost electrons is represented by 2p3.
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What are the atomic numbers of elements whose outermost electrons is represented by 3p5?
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In Milikan’s experiment, static electric charge on the oil drops has been obtained by shining X-rays. If the static electric charge on the oil drop is - 1.282 × 10-18C, calculate the number of electrons present on it.
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Define the bond length.
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For the following equilibrium, Kc = 6.3 × 1014 at 1000 K
\[\ce{NO (g) + O3 (g) ⇌ NO2 (g) + O2 (g)}\]
Both the forward and reverse reactions in the equilibrium are elementary bimolecular reactions. What is Kc, for the reverse reaction?
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Comment on the following observation:
E⊝ for \[\ce{M^{2+}_{(aq)} + 2e– -> M(s)}\] (where M = Ca, Sr or Ba) is nearly constant.
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Describe the effect of addition of H2 on the equilibrium of the reaction:
\[\ce{2H2(g) + CO (g) ⇌ CH3OH (g)}\]
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Describe the effect of Addition of CH3OH on the equilibrium of the reaction:
\[\ce{2H2(g) + CO (g) ⇌ CH3OH (g)}\]
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Describe the effect of Removal of CO on the equilibrium of the reaction:
\[\ce{2H2(g) + CO (g) ⇌ CH3OH (g)}\]
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Describe the effect of Removal of CH3OH on the equilibrium of the reaction:
\[\ce{2H2(g) + CO (g) ⇌ CH3OH (g)}\]
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Among NH3, H2O and HF, which would you expect to have highest magnitude of hydrogen bonding and why?
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Arrange the following:
CaH2, BeH2 and TiH2 in order of increasing electrical conductance.
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Describe the usefulness of water in biosphere and biological systems.
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What properties of water make it useful as a solvent? What types of compound can it (i) dissolve, and (ii) hydrolyse?
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Dihydrogen gas used in Haber’s process is produced by reacting methane from natural gas with high-temperature steam. The first stage of two-stage reaction involves the formation of CO and H2. In the second stage, CO formed in the first stage is reacted with more steam in water gas shift reaction,
\[\ce{CO (g) + H2O (g) ⇌ CO2 (g) + H2 (g)}\]
If a reaction vessel at 400°C is charged with an equimolar mixture of CO and steam such that `"p"_"CO" = "p"_("H"_2"O")` = 4.0 bar, what will be the partial pressure of H2 at equilibrium? Kp = 10.1 at 400°C.
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