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Mention the number of unpaired electrons and geometry of the following complex:
\[\ce{[Ni(CN)4]^2-}\]
Concept: Theories of Bonding in Complexes
Write the name of a hexadentate ligand.
Concept: Types of Ligands
Identify the product ‘D’ in the following sequence of reactions:
\[\ce{H3C - CH2 - CH2 - Cl \underset{KOH}{\overset{Alc}{->}} 'B' \overset{HBr}{->} 'C' \underset{Elther}{\overset{Na}{->}}'D'}\]
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
Identify ‘A’ and ‘B’ in the following reaction :
\[\ce{CH3 - CH = CH2 ->[HBr]'A' ->[alc.KOH]'B'}\]
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
State and explain Markownikoff's rule with suitable example
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
How are the following conversions carried out?
2-methylbutan-1-ol into 2 -methylbutanoic acid.
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
But-1-ene on reaction with HCl in the presence of sodium peroxide yields _______.
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
IUPAC name of is C6H5 − CH2 − C − CH2 − CH2 − CH2 − CH3 is _______
(A) 1-Phenylhexan-2-one
(B) 6-Phenylhexan-5-one
(C) 1-Benzylhexan-5-one
(D) Dodecan-5-one
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
How is nitromethane prepared from the following?
alkyl halide
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
How is nitromethane prepared from the following?
α-nitroalkene
Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
Draw a neat, labelled energy profile diagram for SN1 reaction mechanism.
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
Complete and rewrite the balanced chemical equations

Concept: Introduction to Haloalkanes and Haloarenes >> Nomenclature
What are racemates?
Concept: Hydrocarbons: Alkanes >> Reactions of Haloalkanes - Elimination Reactions
Give reason:
Reactions involving Grignard reagent must be carried out under anhydrous condition.
Concept: Reaction with Active Metals
Give reason:
Alkyl halides are generally not prepared by free radical halogenation of alkanes.
Concept: Methods of Preparation of Alkyl Halides
Complete the following reaction sequence by writing the structural formulae of the organic compound 'A', 'B' and 'C'.
\[\ce{2-Bromobutane->[Alc.KOH]A->[][Br2]B->[][NaNH2]C}\]
Concept: Chemical Properties
The following will react faster by SN1 mechanism
Concept: Chemical Properties
Name the reagent used to convert alkyl halide to ester.
Concept: Methods of Preparation of Alkyl Halides
Explain. Aryl halides are less reactive than alkyl halides towards nucleophilic substitution reactions.
Concept: Chemical Properties
Explain optical activity of 2-chlorobutane.
Concept: Optical Isomerism in Halogen Derivatives
