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Why do the transition elements have higher enthalpies of atomisation?
Concept: Physical Properties of the Transition Elements (d-block)
In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?
Concept: Physical Properties of the Transition Elements (d-block)
Complete the following equation:
\[\ce{2MnO4- + 6H+ + 5NO2- ->}\]
Concept: Important Compounds of Transition Elements
What are the consequences of lanthanoid contraction?
Concept: F-block Elements >> The Lanthanoids
Write the formula of an oxo-anion of Chromium (Cr) in which it shows the oxidation state equal to its group number
Concept: Physical Properties of the Transition Elements (d-block)
Account for the following:
Zn, Cd and Hg are soft metals.
Concept: F-block Elements >> The Lanthanoids
Following are the transition metal ions of 3d series:
Ti4+, V2+, Mn3+, Cr3+
(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)
Answer the following:
1) Which ion is most stable in an aqueous solution and why?
2) Which ion is a strong oxidising agent and why?
3) Which ion is colourless and why?
Concept: Physical Properties of the Transition Elements (d-block)
Complete the following equations:
`2MnO_4^(-)+16H^++5S^(2-)rarr`
Concept: Important Compounds of Transition Elements
How would you account for the following?
Zr (Z = 40) and Hf (Z = 72) have almost identical radii.
Concept: Physical Properties of the Transition Elements (d-block)
Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?
Concept: Physical Properties of the Transition Elements (d-block)
How would you account the following :
Highest fluoride of Mn is MnF4 whereas the highest oxide is Mn2O7.
Concept: F-block Elements >> The Actinoids
Complete the following equation :
Concept: Important Compounds of Transition Elements
Account for the following :
Manganese shows maximum number of oxidation states in 3d series.
Concept: Important Compounds of Transition Elements
E0 value for Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.
Concept: Important Compounds of Transition Elements
Write the chemical equation for the preparation of 4 KMnO from 2. MnO Why does purple colour of acidified permanganate solution decolourise when it oxidises Fe2- to Fe3+ ?
Concept: Important Compounds of Transition Elements
Account for the following :
Ti4+ is colourless whereas V4+ is coloured in an aqueous solutions.
Concept: Physical Properties of the Transition Elements (d-block)
Why do transition metals exhibit higher enthalpy of atomization?
Concept: Physical Properties of the Transition Elements (d-block)
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
Concept: F-block Elements >> The Lanthanoids
What is lanthanoid contraction? Write the.............
Concept: F-block Elements >> The Lanthanoids
Write the ionic equation showing the oxidation of Fe(II) salt by acidified dichromate solutions.
Concept: Important Compounds of Transition Elements
