Advertisements
Advertisements
Question
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2Br + KCN ->[aq{.} ethanol]}\]
Advertisements
Solution
\[\ce{\underset{Bromoethane}{CH3CH2Br} + KCN ->[aq{.} ethanol][(nucleophilic substitution)] \underset{Propanenitrile}{CH3CH2CN} + KBr}\]
APPEARS IN
RELATED QUESTIONS
What are ambident nucleophiles? Explain with an example.
Arrange the compounds of the following set in order of reactivity towards SN2 displacement:
2-Bromo-2-methylbutane, 1-Bromopentane, 2-Bromopentane
In a coordination entity of the type [PtCl2(en)2]2+ which isomer will show optical isomerism?
Most reactive halide towards SN1 reaction is ____________.
Racemic compound has ____________.
Identify the end product (C) in the following sequence:
\[\ce{C2H5OH ->[SOCl2][Pyridine] A ->[KCN {(alc.)}] B ->[2H2O/H^+] C}\]
Which of the following statements are correct about the kinetics of this reaction?

(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
In which reaction mechanism carbocation is formed?
The number of chiral alcohol (s) with molecular formula C4H10O is ______.
The number of chiral carbons present in the molecule given below is ______.

In SN1 reactions, the correct order of reactivity for the following compounds:
CH3Cl, CH3CH2Cl, (CH3)2CHCl and (CH3)3CCl is ______.
Arrange the following compounds in increasing order of reactivity towards SN2 reaction.
2-Bromopentane, 1-Bromopentane, 2-Bromo-2-methylbutane
Retention of configuration is observed in ______.
Complete the reaction with the main product formed:

An organic compound A with the molecular formula (+) C4H9Br undergoes hydrolysis to form (+) C4H9OH. Give the structure of A and write the mechanism of the reaction.
Identify the product in the following reaction: 
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}\ce{CH3CH2CHCH3}\\
\phantom{.....}|\\
\phantom{......}\ce{Br}\\
\end{array}\] or \[\begin{array}{cc}\phantom{.......}\ce{CH3}\\
\phantom{...}|\\
\ce{H3C - C - Br}\\
\phantom{...}|\\
\phantom{.......}\ce{CH3}\\
\end{array}\]
Which alkyl halide from the following pair would you expect to react more rapidly by an SN2 mechanism? Explain your answer.
\[\begin{array}{cc}
\ce{CH3CHCH2CH2Br}\\
|\phantom{.............}\\
\ce{CH3}\phantom{..........}\\
\end{array}\] or \[\begin{array}{cc}
\ce{CH3CH2CHCH2Br}\\
|\\
\phantom{...}\ce{CH3}\\
\end{array}\]
Consider the reactions,
(i) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5OH] \underset{}{(CH3)2CH - CH2OC2H5 + HBr}}\\
\end{array}\]
(ii) \[\begin{array}{cc}
\phantom{}\ce{\underset{}{(CH3)2CH - CH2Br} ->[C2H5O-] \underset{}{(CH3)2CH - CH2OC2H5 + Br-}}\\
\end{array}\]
The mechanisms of reactions (i) and (ii) are respectively:
The compound that will undergo SN1 reaction with the fastest rate is:
