Advertisements
Advertisements
Question
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
Options
1:3 electrolyte
1:2 electrolyte
1:1 electrolyte
3:1 electrolyte
Advertisements
Solution
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to 1:2 electrolyte.
Explanation:
One mole of \[\ce{AgNO3}\] precipitates one mole of chloride ion. In the above reaction, when 0.1 mole \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained thus, there must be two free chloride ions in the solution of electrolyte.
So, molecular formula of complex will be \[\ce{[CO(NH3)5Cl]Cl2}\] and electrolytic solution must contain \[\ce{[CO(NH3)5Cl]^{2+}}\] and two CT as constituent ions. Thus, it is 1:2 electrolyte.
\[\ce{[Co(NH3)5Cl]Cl2 -> [Co(NH3)5Cl]^{2+} (aq) + 2Cl^{-} (aq)}\]
APPEARS IN
RELATED QUESTIONS
What is meant by unidentate ligand?
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
K3[Co(C2O4)3]
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
Write IUPAC names of the following compounds:
Following compounds are given to you :
2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane
1) Write the compound which is most reactive towards SN2 reaction.
2) Write the compound which is optically active.
3) Write the compound which is most reactive towards β-elimination reaction.
Write the structures of compounds A, B and C in the following reactions
Which of the following complexes formed by \[\ce{Cu^2+}\] ions is most stable?
When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.
Which of the following complexes are homoleptic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]
(iii) \[\ce{[Ni(CN)4]^{2-}}\]
(iv) \[\ce{[Ni(NH3)4Cl2]}\]
Match the complex ions given in Column I with the colours given in Column II and assign the correct code:
| Column I (Complex ion) | Column II (Colour) |
| A. \[\ce{[Co(NH3)6]^{3+}}\] | 1. Violet |
| B. \[\ce{[Ti(H2O)6]^{3+}}\] | 2. Green |
| C. \[\ce{[Ni(H2O)6]^{2+}}\] | 3. Pale blue |
| D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] | 4. Yellowish orange |
| 5. Blue |
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
| Column I (Coordination Compound) | Column II (Central metal atom) |
| A. Chlorophyll | 1. rhodium |
| B. Blood pigment | 2. cobalt |
| C. Wilkinson catalyst | 3. calcium |
| D. Vitamin B12 | 4. iron |
| 5. magnesium |
In which of the following compounds, the oxidation number of iodine is fractional?
The oxidation state of Fe in the brown ring complex [F3(H2O)5NO]SO4 is
Metal attached with EDTA in an octahedral complex, has coordination number ______.
The following ligand is:
The one that will show optical activity is: (en = ethane 1, 2-diamine)
Does ionization isomer for the following compound exist? Justify your answer.
\[\ce{Hg[Co(SCN)4]}\]
In the complex ion \[\ce{[CoCl(en)2ONO]+}\], the coordination number and the oxidation number of the central metal ion are ______ and ______.
Give two examples of ambidentate ligands.
Homoleptic complex from the following complex is ____.
