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What is Grignard reagent? How is it prepared? Why are they prepared under anhydrous condition?

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Question

What is Grignard reagent? How is it prepared? Why are they prepared under anhydrous condition?

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Solution

  1. Grignard reagent: When alkyl halide is treated with magnesium in the dry ether as the solvent, it gives alkyl magnesium halide. This is known as the Grignard reagent.
  2. The Grignard reagent can be prepared as,
    \[\ce{\underset{Alkyl halide}{R - X} + Mg ->[dry ether] \underset{\text{Alkyl magnesium halide (Grignard reagent)}}{R - Mg - X}}\]
  3. Grignard reagents are highly reactive compounds.
  4. They react with water or compounds containing hydrogen attached to the electronegative element.
    Hence, reactions involving Grignard reagent must be carried out under anhydrous condition.
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