English

What is Grignard reagent? How is it prepared? Why are they prepared under anhydrous condition? - Chemistry

Advertisements
Advertisements

Question

What is Grignard reagent? How is it prepared? Why are they prepared under anhydrous condition?

Answer in Brief
Advertisements

Solution

  1. Grignard reagent: When alkyl halide is treated with magnesium in the dry ether as the solvent, it gives alkyl magnesium halide. This is known as the Grignard reagent.
  2. The Grignard reagent can be prepared as,
    \[\ce{\underset{Alkyl halide}{R - X} + Mg ->[dry ether] \underset{\text{Alkyl magnesium halide (Grignard reagent)}}{R - Mg - X}}\]
  3. Grignard reagents are highly reactive compounds.
  4. They react with water or compounds containing hydrogen attached to the electronegative element.
    Hence, reactions involving Grignard reagent must be carried out under anhydrous condition.
shaalaa.com
Methods of Preparation of Alkyl Halides
  Is there an error in this question or solution?
Chapter 10: Halogen Derivatives - Short Answer Questions (Type-II)

RELATED QUESTIONS

Write the structure and IUPAC name of the major product in the following reaction.

\[\begin{array}{cc}
\ce{CH3 - CH - CH2Cl + NaI ->[Acetone]}\\
|\phantom{..................}\\
\ce{CH3\phantom{...............}}
\end{array}\]


Write the structure and IUPAC name of the major product in the following reaction.

\[\ce{CH3 - CH2Br + SbF3 ->}\]


Write the structure and IUPAC name of the major product in the following reaction.


Give reason:

Alkyl halides are generally not prepared by free radical halogenation of alkanes.


Convert the following:

But-1-ene to n-butyl iodide


Aromatic electrophilic substitution with iodine can be carried out using _____________


Name the reagent used to convert alkyl halide to ester.


Give reason. Though alkyl halides are moderately polar, they are insoluble in water.


Predict all the alkenes that would be formed by dehydrohalogenation of the following alkyl halide.

  1. 2-chloro-2-methylbutane
  2. 3-bromo-2,2,3-trimethylpentane

Which of the following pairs of aryl halides cannot be prepared directly by electrophilic substitution?


Which among the following methods is not suitable for the preparation of alkyl chlorides?


What is the name of reaction involving replacement of diazonium group by chloride using cuprous (I) salt?


Alkyl fluorides are prepared by heating alkyl bromides or chlorides in the presence of metallic fluorides. The reaction is known as ____________ reaction.


Conversion of an alcohol into alkyl chloride by reacting with thionyl chloride is done in a medium of ____________.


Amongst the following, HBr reacts fastest with


The following reaction is known as:

\[\ce{R - Cl + NaI ->[acetone] R - I + NaCl ↓}\]


What is the relative rate of SN2 reaction for (CH3)3C - Br?


Alkyl chloride when treated with sodium iodide in presence of dry acetone forms alkyl iodide. What is the name of this reaction?


Which one of the following is Swartz reaction?


The conversion of ethyl bromide using sodium iodide and dry acetone, this reaction is know as ______.


Choose the false statement from the following.


Explain Swartz reaction.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×