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Define the Standard enthalpy of combustion - Chemistry

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Question

Define the Standard enthalpy of combustion.

Definition
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Solution

The standard enthalpy of combustion of a substance is the standard enthalpy change accompanying a reaction in which one mole of the substance in its standard state is completely oxidised.

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Thermochemistry
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Chapter 4: Chemical Thermodynamics - Short answer questions (Type- I)

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Answer the following question.

Calculate ΔrH° for the following reaction at 298 K:

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The enthalpy change for the reaction, \[\ce{C2H4_{(g)} + H2_{(g)} -> C2H6_{(g)}}\] is −620 J when 100 mL of ethylene and 100 ml of \[\ce{H2}\] react at 1 bar pressure. Calculate the pressure volume type of work and ΔU for the reaction.


The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.


The enthalpy change of the following reaction:

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Calculate C – Cl bond enthalpy. The bond enthalpies are:

Bond C − H Cl − Cl H − Cl
∆H°/kJ mol−1 414 243 431

Calculate the standard enthalpy of formation of liquid methanol from the following data:

  1. \[\ce{CH3OH_{(l)} + \frac{3}{2} O_{2(g)} -> CO_{2(g)} + 2H2O_{(l)}}\]     ∆H° = – 726 kJ mol–1
  2. \[\ce{C_{(Graphite)} + O_{2(g)} -> CO_{2(g)}}\]          ∆cH° = – 393 kJ mol–1
  3. \[\ce{H_{2(g)} + \frac{1}{2} O_{2(g)} -> H2O_{(l)}}\]          ∆fH° = – 286 kJ mol–1 

When 2 moles of C2H6(g) are completely burnt, 3129 kJ of heat is liberated. If ∆Hf for CO2(g) and H2O(l) are −395 and −286 kJ per mole respectively, the heat combustion of C2H6(g) is ____________.


The volume of oxygen required for complete combustion of 0.25 mole of methane at STP is ______.


Daily requirement of energy of a person is 'x' kJ. If heat of combustion of food material (Molecular mass = 100 g) is 'y' kJ, his daily consumption of the food in gram would be ____________.


The standard heats of formation in kcal mol−1 of NO2(g) and N2O4(g) are 8.0 and 2.0 respectively. The heat of dimerization of NO2 in kcal is ____________.

\[\ce{2NO2_{(g)} ⇌ N2O4_{(g)}}\]


The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.


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Heat of formation of ethane, ethylene acetylene and carbon dioxide are - 136, - 66, - 228 and - 395 (all in kJ) respectively, most stable among them is ______.


Calculate the standard enthalpy of formation of CH3OH(l) from the following data:

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  2. \[\ce{C_{(s)} + O2_{(g)} → CO2_{(g)}Δ_cH^° = – 393 kJ mol^{-1}}\]
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From the following bond energies:

H – H bond energy: 431.37 kJ mol−1

C = C bond energy: 606.10 kJ mol−1

C – C bond energy: 336.49 kJ mol−1

C – H bond energy: 410.50 kJ mol−1

Enthalpy for the given reaction will be:

\[\begin{array}{cc}
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\ce{C = C + H - H -> H - C - C - H}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}
\end{array}\]


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The enthalpy of combustion of S (rhombic) is − 297 kJ mo1-1. Calculate the amount of sulphur required to produce 29. 74 kJ of heat.


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\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1

\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.


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