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Define the Standard enthalpy of combustion - Chemistry

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प्रश्न

Define the Standard enthalpy of combustion.

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उत्तर

The standard enthalpy of combustion of a substance is the standard enthalpy change accompanying a reaction in which one mole of the substance in its standard state is completely oxidised.

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Thermochemistry
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अध्याय 4: Chemical Thermodynamics - Short answer questions (Type- I)

संबंधित प्रश्न

Answer the following in one or two sentences.

What is standard state of a substance?


Answer in brief.

How will you calculate reaction enthalpy from data on bond enthalpies?


The enthalpy change for the reaction, \[\ce{C2H4_{(g)} + H2_{(g)} -> C2H6_{(g)}}\] is −620 J when 100 mL of ethylene and 100 ml of \[\ce{H2}\] react at 1 bar pressure. Calculate the pressure volume type of work and ΔU for the reaction.


Define standard enthalpy of formation.


Write an application of Hess’s law.


Classify the following into intensive and extensive properties.

Pressure, volume, mass, temperature.


The standard heats of formation for CCl4(g), H2O(g), CO2(g), and HCl(g) are −25.5, −57.8, −94.1 and −22.1 kcal mol−1, respectively.

∆H for the reaction

\[\ce{CCl4_{(g)} + 2H2O_{(g)} -> CO2_{(g)} + 4HCl_{(g)}}\] at 298 K


The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.


lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)

\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)

Then, the heat of formation of CO is:


Which among the following salts, solubility decreases with increase in temperature?


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Enthalpy of formation of two compounds x and y are −84 kJ and −156 kJ respectively. Which of the following statements is CORRECT?


Given the reaction,

\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ

How much heat will be evolved in the formation of 60 g of CO2?


Calculate the enthalpy of hydrogenation of C2H4(g), given that the enthalpy of formation of ethane and ethylene are −30.2 kcal and +12.5 kcal respectively.


Combustion of glucose takes place as

\[\ce{C6H12O6_{(s)} + 6O2_{(g)} -> 6CO2_{(g)} + 6H2O_{(g)}}\]; ΔH = −72 kcal mol−1

The energy needed for the production of 1.8 g of glucose by photosynthesis will be ___________.


The enthalpy of formation of nitrogen dioxide is +33.2 kJ mol−1. The enthalpy of the reaction \[\ce{2N2_{(g)} + 4O2_{(g)} -> 4NO2_{(g)}}\]; is ____________.


An ideal gas expands isothermally and reversibly from 10 m3 to 20 m3 at 300 K performing 5 .187 kJ of work on surrounding. Calculate number of moles of gas undergoing expansion. (R = 8.314 J K-1 mol-1)


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


\[\ce{A -> B}\], ∆H = −10 kJ mol−1, Ea(f) = 50 kJ mol−1, then Ea of \[\ce{B -> A}\] will be ______.


What is the amount of water formed by the combustion of 1.6 g methane?


How many moles of helium gas occupies 22.4 Lat 0°c and at 1 atmospheric pressure?


What is enthalpy of formation of NH3 if bond enthalpies as (N ≡ N) = - 941 kJ/mol.

\[\ce{(H - H)}\] = 436 kJ/mol and \[\ce{(N - H)}\] = 389 kJ/mol?


When 0.5 gram of sulphur is burnt to form SO2, 4.6 kJ of heat liberated. Calculate enthalpy of formation of SO2(g). (Atomic mass : S = 32, O = 16)


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[C2H5OH(1)] = - 1409 kJ mol-1


Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.


Draw energy profile diagram and show:

  1. activated complex
  2. energy of activation for forward and backward reactions
  3. enthalpy of reaction

Heat of combustion of CH4(g) is -890 kJ/mole. What is the value of Δc H of 8gm of methane?


Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.


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