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Define the Standard enthalpy of combustion

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प्रश्न

Define the Standard enthalpy of combustion.

परिभाषा
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उत्तर

The standard enthalpy of combustion of a substance is the standard enthalpy change accompanying a reaction in which one mole of the substance in its standard state is completely oxidised.

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अध्याय 4: Chemical Thermodynamics - Short answer questions (Type- I)

संबंधित प्रश्न

Select the most appropriate option.

Which of the following reactions is exothermic?


Answer the following question.

Calculate ΔrH° for the following reaction at 298 K:

1) 2H3BO3(aq) → B2O3(s) + 3H2O(l), ΔrH° = + 14.4 kJ

2) H3BO3(aq) → HBO2(aq) + H2O(l), ΔrH° = - 0.02 kJ

3) H2B4O7(s) → 2B2O3(s) + H2O(l), ΔrH° = + 17.3 kJ


Calculate the standard enthalpy of combustion of CH4(g) if ΔfH°(CH4) = – 74.8 kJ mol–1, ΔfH°(CO2) = – 393.5 kJ mol–1 and ΔfH°(H2O) = – 285.8 kJ mol–1.


Define standard enthalpy of formation.


Calculate the standard enthalpy of formation of liquid methanol from the following data:

  1. \[\ce{CH3OH_{(l)} + \frac{3}{2} O_{2(g)} -> CO_{2(g)} + 2H2O_{(l)}}\]     ∆H° = – 726 kJ mol–1
  2. \[\ce{C_{(Graphite)} + O_{2(g)} -> CO_{2(g)}}\]          ∆cH° = – 393 kJ mol–1
  3. \[\ce{H_{2(g)} + \frac{1}{2} O_{2(g)} -> H2O_{(l)}}\]          ∆fH° = – 286 kJ mol–1 

Define the Enthalpy of ionisation.


Does the following reaction represent a thermochemical equation?

\[\ce{CH_{4(g)} + 2O_{2(g)} -> CO_{2(g)} + 2H2O_{(g)}}\], ∆fH° = –900 kJ mol–1


Daily requirement of energy of a person is 'x' kJ. If heat of combustion of food material (Molecular mass = 100 g) is 'y' kJ, his daily consumption of the food in gram would be ____________.


The standard heats of formation in kcal mol−1 of NO2(g) and N2O4(g) are 8.0 and 2.0 respectively. The heat of dimerization of NO2 in kcal is ____________.

\[\ce{2NO2_{(g)} ⇌ N2O4_{(g)}}\]


lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)

\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)

Then, the heat of formation of CO is:


\[\ce{S + 3/2O2 -> SO3 +2{x} kcal}\] .........(i)

\[\ce{SO2 + 1/2O2 -> SO3 + {y} kcal}\] .......(ii)

The heat of formation of SO2 is ____________.


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


Standard entropies of N2(g), H2(g), and NH3(g) are a1, a2 and a3 J K-1 mol-1 respectively. What is value of ΔS° for formation of NH3(g)?


Which of the following equations has ΔfH° and ΔH° same?


Heat of formation of ethane, ethylene acetylene and carbon dioxide are - 136, - 66, - 228 and - 395 (all in kJ) respectively, most stable among them is ______.


Identify the invalid equation.


\[\ce{A -> B}\], ∆H = −10 kJ mol−1, Ea(f) = 50 kJ mol−1, then Ea of \[\ce{B -> A}\] will be ______.


When the enthalpy of combustion of carbon to carbon dioxide is - 360 kJ mol-1, then the enthalpy change for the formation of 18 g of CO2 from carbon and dioxygen at the same temperature in kJ will be ______.


When 0.5 gram of sulphur is burnt to form SO2, 4.6 kJ of heat liberated. Calculate enthalpy of formation of SO2(g). (Atomic mass : S = 32, O = 16)


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1


Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.


Calculate ΔsubH of the H2O from the given data:
\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1

\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.


Calculate heat evolved for combustion of 13 gm of acetylene (C2H2).

Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]


Heat of combustion of CH4(g) is -890 kJ/mole. What is the value of Δc H of 8gm of methane?


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