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Define the Standard enthalpy of combustion

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प्रश्न

Define the Standard enthalpy of combustion.

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उत्तर

The standard enthalpy of combustion of a substance is the standard enthalpy change accompanying a reaction in which one mole of the substance in its standard state is completely oxidised.

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अध्याय 4: Chemical Thermodynamics - Short answer questions (Type- I)

संबंधित प्रश्न

Answer in brief.

What is the standard enthalpy of combustion? Give an example.


Answer in brief.

How much heat is evolved when 12 g of CO reacts with NO2? The reaction is:

4CO(g)  2NO2(g) → 4CO2(g) + N2(g), ΔrH° = - 1200 kJ


Answer the following question.

Calculate ΔrH° for the following reaction at 298 K:

1) 2H3BO3(aq) → B2O3(s) + 3H2O(l), ΔrH° = + 14.4 kJ

2) H3BO3(aq) → HBO2(aq) + H2O(l), ΔrH° = - 0.02 kJ

3) H2B4O7(s) → 2B2O3(s) + H2O(l), ΔrH° = + 17.3 kJ


The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.


Calculate the standard enthalpy of the reaction.

\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]

Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

A compound that has a high negative heat of formation is normally ____________.


When 6.0 g of graphite reacts with dihydrogen to give methane gas, 37.4 kJ of heat is liberated. What is standard enthalpy of formation of CH4 (g)?


The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.


lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)

\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)

Then, the heat of formation of CO is:


\[\ce{S + 3/2O2 -> SO3 +2{x} kcal}\] .........(i)

\[\ce{SO2 + 1/2O2 -> SO3 + {y} kcal}\] .......(ii)

The heat of formation of SO2 is ____________.


Which among the following salts, solubility decreases with increase in temperature?


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Which of the following compounds is Not present in its standard state at 25°C and 1 atmosphere pressure?


Combustion of glucose takes place as

\[\ce{C6H12O6_{(s)} + 6O2_{(g)} -> 6CO2_{(g)} + 6H2O_{(g)}}\]; ΔH = −72 kcal mol−1

The energy needed for the production of 1.8 g of glucose by photosynthesis will be ___________.


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


What is the amount of water formed by the combustion of 1.6 g methane?


When the enthalpy of combustion of carbon to carbon dioxide is - 360 kJ mol-1, then the enthalpy change for the formation of 18 g of CO2 from carbon and dioxygen at the same temperature in kJ will be ______.


The enthalpy change that accompanies a reaction in which 1 mole of its standard state is formed from its elements in their standard states


Define and explain the term, enthalpy of reaction.


Calculate the standard enthalpy of the reaction, \[\ce{SiO2_{(s)} + 3C_{(graphite)} -> SiC_{(s)} + 2CO_{(g)}}\] from the following reactions:

  1. \[\ce{Si_{(s)} + O2_{(g)} -> SiO2_{(s)}}\], ΔrH0 = −911 kJ
  2. \[\ce{2C_{(graphite)} + O2_{(g)} -> 2CO_{(g)}}\], ΔrH= −221 kJ
  3. \[\ce{Si_{(s)} + C_{(graphite)} -> SiC_{(s)}}\], ΔrH= −65.3 kJ

Which of the following reactions defines the enthalpy of formation?


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[C2H5OH(1)] = - 1409 kJ mol-1


Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.


For the reaction, aA + bB → cC + dD, write the expression for enthalpy change of reaction in terms of enthalpies of formation of reactants and products.


The enthalpy of combustion of S (rhombic) is − 297 kJ mo1-1. Calculate the amount of sulphur required to produce 29. 74 kJ of heat.


Heat of combustion of CH4(g) is -890 kJ/mole. What is the value of Δc H of 8gm of methane?


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