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Define the Enthalpy of ionisation.

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प्रश्न

Define the Enthalpy of ionisation.

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उत्तर

Enthalpy of ionization is the enthalpy change accompanying the removal of an electron from one mole of a gaseous atom.

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अध्याय 4: Chemical Thermodynamics - Long answer questions

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Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

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Enthalpy for the given reaction will be:

\[\begin{array}{cc}
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\ce{C = C + H - H -> H - C - C - H}\\
\phantom{.}|\phantom{....}|\phantom{....................}|\phantom{....}|\phantom{.....}\\
\phantom{}\ce{H}\phantom{...}\ce{H}\phantom{...................}\ce{H}\phantom{...}\ce{H}\phantom{....}
\end{array}\]


Identify the invalid equation.


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How many moles of helium gas occupies 22.4 Lat 0°c and at 1 atmospheric pressure?


When the enthalpy of combustion of carbon to carbon dioxide is - 360 kJ mol-1, then the enthalpy change for the formation of 18 g of CO2 from carbon and dioxygen at the same temperature in kJ will be ______.


What is enthalpy of formation of NH3 if bond enthalpies as (N ≡ N) = - 941 kJ/mol.

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