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Define standard enthalpy of formation. - Chemistry

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प्रश्न

Define standard enthalpy of formation.

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उत्तर

The standard enthalpy of formation of a compound is the enthalpy change that accompanies a reaction in which one mole of pure compound in its standard state is formed from its elements in their standard states.

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Thermochemistry
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अध्याय 4: Chemical Thermodynamics - Short answer questions (Type- II)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
अध्याय 4 Chemical Thermodynamics
Short answer questions (Type- II) | Q 4

संबंधित प्रश्न

Answer the following in one or two sentences.

What is standard state of a substance?


Answer in brief.

What is the standard enthalpy of combustion? Give an example.


The standard enthalpy of formation of water is - 286 kJ mol-1. Calculate the enthalpy change for the formation of 0.018 kg of water.


State and explain Hess’s law of constant heat summation.


Calculate the standard enthalpy of combustion of CH4(g) if ΔfH°(CH4) = – 74.8 kJ mol–1, ΔfH°(CO2) = – 393.5 kJ mol–1 and ΔfH°(H2O) = – 285.8 kJ mol–1.


Calculate the standard enthalpy of the reaction.

\[\ce{2Fe_{(s)} + \frac{3}{2} O_{2(g)} -> Fe2O_{3(s)}}\]

Given:

1. \[\ce{2Al_{(s)} + Fe2O_{3(s)} -> 2Fe_{(s)} + Al_2O_{3(s)}}\], rH° = –847.6 kJ
2. \[\ce{2Al_{(s)} + \frac{3}{2} O_{2(g)} -> Al2O_{3(s)}}\], rH° = –1670 kJ

Does the following reaction represent a thermochemical equation?

\[\ce{CH_{4(g)} + 2O_{2(g)} -> CO_{2(g)} + 2H2O_{(g)}}\], ∆fH° = –900 kJ mol–1


A compound that has a high negative heat of formation is normally ____________.


The volume of oxygen required for complete combustion of 0.25 mole of methane at STP is ______.


When 6.0 g of graphite reacts with dihydrogen to give methane gas, 37.4 kJ of heat is liberated. What is standard enthalpy of formation of CH4 (g)?


The standard heats of formation for CCl4(g), H2O(g), CO2(g), and HCl(g) are −25.5, −57.8, −94.1 and −22.1 kcal mol−1, respectively.

∆H for the reaction

\[\ce{CCl4_{(g)} + 2H2O_{(g)} -> CO2_{(g)} + 4HCl_{(g)}}\] at 298 K


lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)

\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)

Then, the heat of formation of CO is:


\[\ce{S + 3/2O2 -> SO3 +2{x} kcal}\] .........(i)

\[\ce{SO2 + 1/2O2 -> SO3 + {y} kcal}\] .......(ii)

The heat of formation of SO2 is ____________.


Which among the following salts, solubility decreases with increase in temperature?


The heat evolved in the combustion of benzene is given by

\[\ce{C6H6 + 7 1/2O2 -> 6CO2_{(g)} + 3H2O_{(l)}}\]; ΔH = −3264.6 kJ

Which of the following quantities of heat energy will be evolved when 39 g C6H6 are burnt?


Given the reaction,

\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ

How much heat will be evolved in the formation of 60 g of CO2?


The enthalpy of formation of nitrogen dioxide is +33.2 kJ mol−1. The enthalpy of the reaction \[\ce{2N2_{(g)} + 4O2_{(g)} -> 4NO2_{(g)}}\]; is ____________.


Standard enthalpy of formation of water is - 286 kJ mol-1. When 1800 mg of water is formed from its constituent elements in their standard states the amount of energy liberated is ______.


An ideal gas expands isothermally and reversibly from 10 m3 to 20 m3 at 300 K performing 5 .187 kJ of work on surrounding. Calculate number of moles of gas undergoing expansion. (R = 8.314 J K-1 mol-1)


Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?


Identify the invalid equation.


Calculate the standard enthalpy of the reaction, \[\ce{SiO2_{(s)} + 3C_{(graphite)} -> SiC_{(s)} + 2CO_{(g)}}\] from the following reactions:

  1. \[\ce{Si_{(s)} + O2_{(g)} -> SiO2_{(s)}}\], ΔrH0 = −911 kJ
  2. \[\ce{2C_{(graphite)} + O2_{(g)} -> 2CO_{(g)}}\], ΔrH= −221 kJ
  3. \[\ce{Si_{(s)} + C_{(graphite)} -> SiC_{(s)}}\], ΔrH= −65.3 kJ

Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[C2H5OH(1)] = - 1409 kJ mol-1


Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.

ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1


Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.


Calculate heat evolved for combustion of 13 gm of acetylene (C2H2).

Given: \[\ce{C2H2_{(g)} + 5/2O_{2(g)}-> 2CO_{2(g)} + H2O_{(l)} \Delta_{(c)}H^{0} = - 1300 kJ}\]


Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.


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