Advertisements
Advertisements
Question
The enthalpy change of the following reaction:
\[\ce{CH_{4(g)} + Cl_{2(g)} -> CH3Cl_{(g)} + HCl_{(g)}ΔH^0 = –104 kJ}\]
Calculate C – Cl bond enthalpy. The bond enthalpies are:
| Bond | C − H | Cl − Cl | H − Cl |
| ∆H°/kJ mol−1 | 414 | 243 | 431 |
Advertisements
Solution
Given: ΔrH0 = –104 kJ
ΔH0 (C – H) = 414 kJ mol–1
ΔH0 (Cl – Cl) = 243 kJ mol–1
ΔH0 (H – Cl) = 431 kJ mol–1
To find: C – Cl bond enthalpy, ΔH0 (C – Cl)
Formula: ΔrH0 = ∑ΔH°(reactant bonds) − ∑ΔH0 (product bonds)
Calculation: ΔrH0 = Σ ΔH0 (reactant bonds) – Σ ΔH0 (product bonds)
= [4 ΔH0(C – H) + ΔH°(Cl – Cl)] – [3 ΔH0(C – H) + ΔH0(C – Cl) + ΔH0(H – Cl)]
= ΔH0(C – H) + ΔH0(Cl – Cl) – ΔH0(C – Cl) – ΔH0(H – Cl) –104 kJ
∴ = 1 mol × (414 kJ mol–1) + 1 mol × (243 kJ mol–1) – ΔH0(C – Cl) – 1 mol × (431 kJ mol–1)
∴ –104 kJ = 226 kJ – ΔH°(C – Cl)
∴ ΔH0(C – Cl) = 226 kJ + 104 kJ
∴ ΔH0(C – Cl) = 330 kJ mol–1
C – Cl bond enthalpy is 330 kJ mol–1.
APPEARS IN
RELATED QUESTIONS
Answer the following in one or two sentences.
What is standard state of a substance?
Answer in brief.
How will you calculate reaction enthalpy from data on bond enthalpies?
The enthalpy change for the reaction, \[\ce{C2H4_{(g)} + H2_{(g)} -> C2H6_{(g)}}\] is −620 J when 100 mL of ethylene and 100 ml of \[\ce{H2}\] react at 1 bar pressure. Calculate the pressure volume type of work and ΔU for the reaction.
Define the Enthalpy of ionisation.
Does the following reaction represent a thermochemical equation?
\[\ce{CH_{4(g)} + 2O_{2(g)} -> CO_{2(g)} + 2H2O_{(g)}}\], ∆fH° = –900 kJ mol–1
When 2 moles of C2H6(g) are completely burnt, 3129 kJ of heat is liberated. If ∆Hf for CO2(g) and H2O(l) are −395 and −286 kJ per mole respectively, the heat combustion of C2H6(g) is ____________.
The standard heats of formation for CCl4(g), H2O(g), CO2(g), and HCl(g) are −25.5, −57.8, −94.1 and −22.1 kcal mol−1, respectively.
∆H for the reaction
\[\ce{CCl4_{(g)} + 2H2O_{(g)} -> CO2_{(g)} + 4HCl_{(g)}}\] at 298 K
The standard heats of formation in kcal mol−1 of NO2(g) and N2O4(g) are 8.0 and 2.0 respectively. The heat of dimerization of NO2 in kcal is ____________.
\[\ce{2NO2_{(g)} ⇌ N2O4_{(g)}}\]
The enthalpy change accompanying a reaction in which 1 mole of the substance in the standard state reacts completely with oxygen or is completely burnt is called as ____________.
lf, \[\ce{C_{(s)} + O2_{(g)} -> CO2_{(g)}}\], ∆H = x .........(i)
\[\ce{CO_{(g)} + 1/2O2_{(g)} -> CO2_{(g)}}\], ∆H = y .......(ii)
Then, the heat of formation of CO is:
Enthalpy of formation of two compounds x and y are −84 kJ and −156 kJ respectively. Which of the following statements is CORRECT?
Given the reaction,
\[\ce{CH2O_{(g)} + O2_{(g)} -> CO2_{(g)} + H2O_{(g)}}\] ΔH = −527 kJ
How much heat will be evolved in the formation of 60 g of CO2?
Calculate the enthalpy of hydrogenation of C2H4(g), given that the enthalpy of formation of ethane and ethylene are −30.2 kcal and +12.5 kcal respectively.
Heat of formation of water is - 272 kJ mol-1. What quantity of water is converted to H2 and O2 by 750 kJ of heat?
Heat of formation of ethane, ethylene acetylene and carbon dioxide are - 136, - 66, - 228 and - 395 (all in kJ) respectively, most stable among them is ______.
Calculate the standard enthalpy of:
\[\ce{N2H_{4(g)} + H_{2(g)} -> 2NH_{3(g)}}\]
If ΔH0(N – H) = 389 kJ mol–1, ΔH0(H – H) = 435 kJ mol–1, ΔH0(N – N) = 159 kJ mol–1.
What is the amount of water formed by the combustion of 1.6 g methane?
The enthalpy change that accompanies a reaction in which 1 mole of its standard state is formed from its elements in their standard states
Standard enthalpy of combustion of a substance is given. Then Write thermochemical equation.
ΔcH0[CH3CHO(l)] = - 1166 kJ mol-1
Heat of combustion of methane is - 890 kJ/mol. On combustion of 12 gm of methane in excess of oxygen, ______ heat is evolved.
For the reaction, aA + bB → cC + dD, write the expression for enthalpy change of reaction in terms of enthalpies of formation of reactants and products.
The enthalpy of combustion of S (rhombic) is − 297 kJ mo1-1. Calculate the amount of sulphur required to produce 29. 74 kJ of heat.
For the reaction, H2 + I2 ⇌ 2HI; ΔH = 12.4 kcal. The heat of formation of HI, ΔHf = ______.
Calculate ΔsubH of the H2O from the given data:
\[\ce{H2O_{(s)}->H2O_{(l)},}\] ΔfusH = 6.01kJ mol−1
\[\ce{H2O_{(l)}-> H2O_{(g)},}\] ΔVapH = 45.07 kJ mol−1.
Calculate the standard enthalpy of combustion of methane if the standard enthalpy of formation of methane, carbon dioxide and water are −74.8, −393.5 and −285.8 kJmol−1 respectively.
