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Using Sodium Hydroxide Solution, How Would You Distinguish: Ammonium Sulphate from Sodium Sulphate.

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Question

Using Sodium hydroxide solution, how would you distinguish: Ammonium sulphate from sodium sulphate.

Short/Brief Note
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Solution

Ammonium sulphate on reacting with sodium hydroxide liberates ammonia gas:
\[\ce{NH4)2SO4(aq) + 2NaOH(I) -> Na2SO4(aq) + 2NH3(I) + 2H2O(I)}\]
Sodium sulphate on reacting with sodium hydroxide undergoes the following change:
\[\ce{NaOH + Na2SO4 -> NaOH + Na2SO4}\]
However the products would be the same as the reactants, therefore providing no observation for a visible chemical reaction.

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Action of Sodium Hydroxide Solution on Certain Metallic Salt Solutions
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Chapter 18: Practical Work - Exercises [Page 307]

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Frank Chemistry Part 2 [English] Class 10 ICSE
Chapter 18 Practical Work
Exercises | Q 10. (a) | Page 307

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