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Name a yellow monoxide that dissolves in hot and concentrated caustic alkali.

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Question

Name a yellow monoxide that dissolves in hot and concentrated caustic alkali.

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Solution

Lead monoxide (PbO)

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Action of Sodium Hydroxide Solution on Certain Metallic Salt Solutions
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Chapter 4: Analytical Chemistry - EXERCISE-4 [Page 73]

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S.P. Singh Concise Chemistry [English] Class 10 ICSE
Chapter 4 Analytical Chemistry
EXERCISE-4 | Q (B) 3. (f) | Page 73

RELATED QUESTIONS

What do you observe when caustic soda solution is added to the following solution, first a little and then in excess:

Pb(NO3)2

Write balanced equation for this reaction.


Distinguish by adding:
(a) sodium hydroxide solution and
(b) Ammonium hydroxide solution to
(i) Calcium salt solution and lead salt solution
(ii) Lead salt solution and ferrous salt solution
(iii) copper salt solution and ferrous salt solution
(iv) Fe (II) salt solution and Fe (III) Salt solution
(v) Ferrous nitrate and lead nitrate


What do you observe when ammonium salt is heated with caustic soda solution?


Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution respectively. Each solution is divided into two portions (i) and (ii). Describe the effect of

  1. adding sodium hydroxide solution to each portion in turn till it is in excess.
  2. adding ammonium hydroxide to each portion in turn till it is in excess.

Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).

Aqueous salt solution Colour of precipitate when NaOH is added in a small quantity Nature of precipitate (soluble or insoluble) when NaOH is added in excess
Copper (II) sulphate (i) (vi)
Zinc nitrate (ii) (vii)
Lead nitrate (iii) (viii)
Calcium chloride (iv) (ix)
Iron (III) Sulphate (v) (x)

Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.

List X List Y
(i) Pb2+ (A) Reddish Brown
(ii) Fe2+ (B) White insoluble inexcess
(iii) Zn2+ (C) Dirty green
(iv) Fe3+ (D) White soluble in excess
(v) Cu2+ (E) White soluble in excess
(vi) Ca2+ (F) Blue

Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to calcium salt solution and lead salt solution.


Distinguish by adding:

Sodium hydroxide solution and ammonium hydroxide solution to ferrous nitrate and lead nitrate.


Identify the cation in the following case:

Sodium hydroxide solution when added to Solution C gives a white precipitate which is insoluble in excess of sodium hydroxide solution.


Write the word equation when ammonium salt is heated with caustic soda solution.


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