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Question
Using sodium hydroxide solution, how will you distinguish:
Lead hydroxide from magnesium hydroxide.
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Solution
Lead hydroxide from magnesium hydroxide.
When sodium hydroxide is added, lead hydroxide is dissolved in it but when sodium hydroxide is added to magnesium hydroxide, there is no visible reaction i.e. it remains insoluble.
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RELATED QUESTIONS
Sodium hydroxide solution is added to solution A. A white precipitate is formed which is soluble in excess sodium hydroxide. Name the metal ion present in A.
Three test tubes contain calcium nitrate solution, zinc nitrate solution and lead nitrate solution respectively. Each solution is divided into two portions (i) and (ii). Describe the effect of
- adding sodium hydroxide solution to each portion in turn till it is in excess.
- adding ammonium hydroxide to each portion in turn till it is in excess.
Choose the correct answer from the options given below :
Hydroxide of this metal is soluble is sodium hydroxide solution
A white solid A when heated with sodium hydroxide solution, gives a pungent gas B, which turns red litmus blue. The solid, when dissolved in dilute nitric acid and treated with silver nitrate gives a white precipitate of C which is soluble in an ammonia solution.
Sodium hydroxide solution is added first in a small quantity, then in excess to the aqueous salt solutions of copper (II) sulphate, zinc nitrate, lead nitrate, calcium chloride, and iron (III) sulphate. Copy the following table and write the colour of the precipitate in (i) to (v) and the nature of the precipitate (soluble or insoluble) in (vi) to (x).
| Aqueous salt solution | Colour of precipitate when NaOH is added in a small quantity | Nature of precipitate (soluble or insoluble) when NaOH is added in excess |
| Copper (II) sulphate | (i) | (vi) |
| Zinc nitrate | (ii) | (vii) |
| Lead nitrate | (iii) | (viii) |
| Calcium chloride | (iv) | (ix) |
| Iron (III) Sulphate | (v) | (x) |
Sodium hydroxide solution is added to the solutions containing the ions mentioned in List X. List Y gives the details of the precipitate. Match the ions with their coloured precipitates.
| List X | List Y |
| (i) Pb2+ | (A) Reddish Brown |
| (ii) Fe2+ | (B) White insoluble inexcess |
| (iii) Zn2+ | (C) Dirty green |
| (iv) Fe3+ | (D) White soluble in excess |
| (v) Cu2+ | (E) White soluble in excess |
| (vi) Ca2+ | (F) Blue |
State your observation of the following case :
When excess sodium hydroxide is added to calcium nitrate solution
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to lead nitrate solution and zinc nitrate solution.
Distinguish by adding:
Sodium hydroxide solution and ammonium hydroxide solution to Fe(II) salt solution and Fe(III) salt solution.
What is observed when hot, concentrated caustic soda solution is added to zinc? Write a balanced equation.
