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Question
The following compounds will give positive Fehling’s test.
Options
Propanone
Pentan-3-one
Butanone
Butanal
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Solution
Butanal
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Answer in brief.
Observe the following equation of reaction of Tollens' reagent with aldehyde. How do we know that a redox reaction has taken place? Explain.
\[\ce{R-CHO + 2Ag(NH_{3})^{+}_{2} + OH^{-}->[\triangle] R-CO{O}^{-} + 2Ag↓ + 4NH3 + 2H2O}\]
Compounds of general formula, are called ____________.
\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{....}\ce{OR''}\phantom{}\\ \phantom{}\backslash\phantom{..}/\\ \ce{C}\\ \phantom{}/\phantom{..}\backslash\\ \phantom{...}\ce{R'}\phantom{...}\ce{OR''}\phantom{} \end{array}\]
\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{.................}\ce{R}\phantom{..}\ce{H}\phantom{................}\\ \phantom{...}\backslash\phantom{..................}\backslash/\phantom{..........}\phantom{.......}\\ \ce{C = O ->[H2NNH2][KOH/glycol] C + N2 + H2O}\\ \phantom{}/\phantom{............}\phantom{.......}/\phantom{}\backslash\phantom{...............}\\ \phantom{}\ce{R}\phantom{..................}\ce{R}\phantom{..}\ce{H}\phantom{...............} \end{array}\]
Reaction is called ____________.
An aldehyde or ketone reacts with hydrogen cyanide to form corresponding cyanohydrin derivatives. This reaction is an example of ____________.
Acetone on Clemmensen reduction gives ____________.
Compounds of general formula, are called ____________.
\[\begin{array}{cc} \phantom{...}\ce{R}\phantom{....}\ce{OR'}\phantom{}\\ \phantom{}\backslash\phantom{..}/\\ \ce{C}\\ \phantom{}/\phantom{..}\backslash\\ \phantom{...}\ce{H}\phantom{....}\ce{OR'}\phantom{} \end{array}\]
The first oxidation product of secondary alcohols is ____________.
Which of the following is Clemmensen reduction?
Which of the following reagents is used for the following conversion?
\[\ce{CH3 - CH = CH - CHO -> CH3 - CH = CH - CH2OH}\]
Identify the product Y in the following series of reactions.
\[\ce{4-Nitrotoluene ->[(CH3CO)2O/CrO3][273 - 278 K] X ->[H3O^+][\Delta] Y}\]
How is the following conversion effected propanal into butanone?
Complete the following reaction.
\[\begin{array}{cc}
\ce{CH3 - CH2 - CH2 - C - CH3 ->[HO - CH2 - CH2 - CH2 - OH][dry HCl] ?}\\
||\phantom{.........}\\
\ce{O}\phantom{.........}
\end{array}\]
How will you prepare acetic anhydride from acetic acid?
How propanal is converted into propane.
Primary nitroalkanes are obtained in good yield by oxidising aldoximes with the help of ______.
Which of the following compound will give positive iodoform test?
Which of the following compounds does not undergo a haloform reaction?
Write a note on Clemmensen reduction.
Write the structure of the products obtained from the following ketones by action of hydrazine in presence of a slightly acidic medium.
Identify B in the following reaction:
\[\begin{array}{cc}
\ce{O}\phantom{........}\\
||\phantom{........}\\
\ce{\underset{(Acetone)}{CH3 - C - CH3}->[CrO3] B}
\end{array}\]
Write the structure of the major product of the aldol condensation of benzaldehyde with acetone.
Write the structure of the major product of the aldol condensation of benzaldehyde with acetone.
Write the structure of the major product of the aldol condensation of benzaldehyde with acetone.
How will you prepare Acetic anhydride from acetic acid.
Nitration of the compound is carried out; this compound gives a red-orange ppt. with 2,4-DNP, this compound undergoes the Cannizzaro reaction but not aldol, then possible product due to nitration is:
