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Ln which of the following reactions, both oxidised and reduced forms of the same compound are obtained?

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Question

ln which of the following reactions, both oxidised and reduced forms of the same compound are obtained?

Options

  • Aldol condensation 

  • Cannizzaro's reaction

  • Riemer-Tiemann reaction

  • Kolbe's synthesis

MCQ
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Solution

Cannizzaro's reaction

Explanation:

The oxidised and reduced versions of the same aldehyde are generated in Cannizzaro's reaction. It's a reaction of disproportionation.

\[\begin{array}{cc}
\ce{O}\phantom{.................................................................}\\
||\phantom{.................................................................}\\
\ce{\underset{Formaldehyde (No α-H atom)}{2H - C - H} + \underset{{(50%)}}{NaOH} -> \underset{Methyl alcohol (reduced product)}{CH3 - OH} + \underset{Sodium formate (oxidised product)}{HCOONa}}
\end{array}\]

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Chemical Properties of Aldehydes and Ketones
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