Advertisements
Advertisements
Question
State Hund’s rule of maximum multiplicity with a suitable example.
Advertisements
Solution
Hund’s rule of maximum multiplicity:
- Statement: “Pairing of electrons in the orbitals belonging to the same subshell does not occur unless each orbital belonging to that subshell has got one electron each.”
- For example, according to Hund’s rule, each of the three-degenerate p-orbitals must get one electron of parallel spin before anyone of them receives the second electron of opposite spin. Therefore, the configuration of four electrons occupying p-orbitals is represented as
and not as↑↓ ↑ ↑ ↑↓ ↑↓ - As a result of Hund’s rule, the atom with fully filled and half-filled set of degenerate orbitals has extra stability.
APPEARS IN
RELATED QUESTIONS
Using s, p, d notations, describe the orbital with the following quantum numbers n = 4; l =3.
State Heisenberg uncertainty principle.
Define the term Electronic configuration.
Explain the anomalous behaviour of chromium.
Write orbital notations for the electron in orbitals with the following quantum numbers.
n = 4, l = 2
Write condensed orbital notation of electronic configuration of the following element:
Carbon (Z = 6)
Draw shapes of 2s orbitals.
If n = 3, what are the quantum number l and m?
Write a note on ‘Principal Quantum number.
Using the concept of quantum numbers, calculate the maximum numbers of electrons present in the ‘M’ shell. Give their distribution in shells, subshells, and orbitals.
The principal quantum number (n) and magnetic quantum number (ml) for the valence electrons of rubidium atom (Z = 37) are ____________ respectively.
The designation of a subshell with n = 6 and l = 2 is ____________.
Which one of the following orders is CORRECT in case of energy of the given subshells?
P: n = 4; l = 3
Q: n = 5; I = 1
R: n = 5; l = 0
S: n = 4; l = 2
How many electrons in 19K have n = 3, l = 1?
Which of the following options does not represent ground state electronic configuration of an atom?
The probability density plots of 1s and 2s orbitals are given in Figure:
The density of dots in a region represents the probability density of finding electrons in the region.
On the basis of above diagram which of the following statements is incorrect?
Number of angular nodes for 4d orbital is ______.
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (ii) | (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iii) | (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
Which of the following sets of quantum numbers are correct?
| `n` | `l` | `m_l` | |
| (i) | 1 | 1 | +2 |
| (ii) | 2 | 1 | +1 |
| (iii) | 3 | 2 | –2 |
| (iv) | 3 | 4 | –2 |
Which of the following statements concerning the quantum numbers are correct?
(i) Angular quantum number determines the three dimensional shape of the orbital.
(ii) The principal quantum number determines the orientation and energy of the orbital.
(iii) Magnetic quantum number determines the size of the orbital.
(iv) Spin quantum number of an electron determines the orientation of the spin of electron relative to the chosen axis.
Which of the following orbitals are degenerate?
3dxy, 4dxy 3dz2, 3dyz, 4dyz, 4dz2
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
1s, 2s, 3s, 2p
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, arrange the following orbitals in the increasing order of energy.
5f, 6d, 7s, 7p
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
Choose the INCORRECT statement
In assigning R - S configuration, which among the following groups has highest priority?
What are the possible values of magnetic quantum number for p orbital?
