English

Radioactive decay follows first-order kinetics. The initial amount of two radioactive elements X and Y is 1 gm each. What will be the ratio of X and Y after two days if their half- lives

Advertisements
Advertisements

Question

Radioactive decay follows first-order kinetics. The initial amount of two radioactive elements X and Y is 1 gm each. What will be the ratio of X and Y after two days if their half-lives are 12 hours and 16 hours respectively?

Numerical
Advertisements

Solution

For first-order reaction

half life of X = 12 hours

2 days = 48 hours means 4 half lives,

Amount of X left = `1/16` of initial value

half life of Y = 16 hours

2 days = 48 hours means 3 half lives,

Amount left = `1/8` of initial value

Ratio of X : Y = 1 : 2

shaalaa.com
  Is there an error in this question or solution?
2023-2024 (March) Board Sample Paper

RELATED QUESTIONS

A first order reaction has a rate constant 1.15 × 10−3 s−1. How long will 5 g of this reactant take to reduce to 3 g?


The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume.

\[\ce{SO2Cl2_{(g)} -> SO2_{(g)} + Cl2_{(g)}}\]

Experiment Time/s–1 Total pressure/atm
1 0 0.5
2 100 0.6

Calculate the rate of the reaction when total pressure is 0.65 atm.


The rate constant for a first order reaction is 60 s−1. How much time will it take to reduce the initial concentration of the reactant to its `1/16`th value?


The time required for 10% completion of a first order reaction at 298 K is equal to that required for its 25% completion at 308 K. If the value of A is 4 × 1010 s−1. Calculate k at 318 K and Ea.


 A first order reaction is 50% complete in 25 minutes. Calculate the time for 80% completion of the reaction.


Observe the graph shown in figure and answer the following questions:

  1. What is the order of the reaction?
  2. What is the slope of the curve?
  3. Write the relationship between k and t1/2 (half life period).

The decomposition of formic acid on gold surface follows first-order kinetics. If the rate constant at 300 K is 1.0 × 10−3 s−1 and the activation energy Ea = 11.488 kJ mol−1, the rate constant at 200 K is ______ × 10−5 s−1. (Round off to the Nearest Integer)

(Given R = 8.314 J mol−1 K−1)


The slope in the plot of `log  ["R"]_0/(["R"])` Vs. time for a first-order reaction is ______.


How will you represent first order reactions graphically?


The following data were obtained during the decomposition of SO2Cl2 at the constant volume. SO2Cl2 →SO2(g) + Cl2(g)

Time (s) Total Pressure (bar)
0 0.5
100 0.6

Calculate the rate constant of the reaction.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×