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Question
Name the following halide according to the IUPAC system and classify it as an alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halide:
CH3CH2CH(CH3)CH(C2H5)Cl
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Solution
\[\begin{array}{cc}
\ce{CH3}\phantom{...}\ce{Cl}\phantom{.}\\
|\phantom{.........}|\phantom{..}\\
\ce{CH3 - CH2 - CH - CH - CH2 - CH3}\\
\end{array}\]
IUPAC Name: 3-chloro-4-methylhexane
Classification: Secondary (2°) alkyl halide
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\[\begin{array}{cc}
\phantom{}\ce{HO}\phantom{.....}\ce{OH}\phantom{..}\ce{H}\phantom{.....}\ce{O}\phantom{..}\\
\phantom{..}\backslash\phantom{.....}|\phantom{....}|\phantom{.....}//\phantom{.}\\
\ce{\overset{a}{C} - \overset{b}{C} - \overset{c}{C} - \overset{d}{C}}\\
\phantom{..}//\phantom{.....}|\phantom{....}|\phantom{....}\phantom{.}\backslash\phantom{...}\\
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| Column I | Column II | |
| (i) | \[\begin{array}{cc} \ce{CH3 - CH - CH3}\\ |\phantom{..}\\ \ce{X}\phantom{..} \end{array}\] |
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| (ii) | \[\ce{CH2 = CH - CH2 - X}\] | (b) Alkyl halide |
| (iii) | ![]() |
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