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Questions
How will you bring about the following conversion?
Propene to 1-nitropropane
How will you bring about the following conversion in not more than two steps?
Propene to 1-nitropropane
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Solution 1
\[\ce{\underset{Propene}{CH3 - CH = CH2} ->[HBr, ROOR][benzoyl peroxide] \underset{1-Bromopropane}{CH3 - CH2 - CH2 - Br} ->[AgNO2, C2H5OH/H2O][-AgBr] \underset{1-Nitropropane}{CH3 - CH2 - CH2 - NO2}}\]
Solution 2
\[\ce{\underset{Propene}{CH3 - CH = CH2} ->[HBr][Benzoyl peroxide]\underset{1-Bromopropane}{CH3CH2CH2Br} ->[AgONO, Δ][-AgBr]\underset{1-Nitropropane}{CH3CH2CH2-NO2}}\]
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\[\begin{array}{cc}
\ce{H3C}\phantom{..................................}\\
\backslash\phantom{...........................}\\
\ce{CH - CH2 - CH3}\\
/\phantom{...........................}\\
\ce{H3C}\phantom{...................................}
\end{array}\]
