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Karnataka Board PUCPUC Science 2nd PUC Class 12

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields three isomeric monochlorides.

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Question

Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields three isomeric monochlorides.

Short Answer
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Solution

\[\ce{\underset{n-pentane}{CH3 - CH2 - CH2 - CH2 - CH3}}\]

\[\ce{\overset{a}{C}H3\overset{b}{C}H2\overset{c}{C}H2\overset{b}{C}H2\overset{a}{C}H3}\] has three sets of identical H-atoms, denoted as a, b and c. Displacement of any identical hydrogen from each set gives the same product. Hence, three isomeric monochlorides are possible.

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Chapter 6: Haloalkanes and Haloarenes - Intext Question [Page 167]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 6 Haloalkanes and Haloarenes
Intext Question | Q 6.4 (ii) | Page 167

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