Advertisements
Advertisements
Question
How the following conversion can be carried out?
tert-Butyl bromide to isobutyl bromide
Advertisements
Solution
\[\begin{array}{cc}
\ce{CH3}\phantom{..............................................}\ce{CH3}\phantom{......................................}\ce{CH3}\phantom{....}\\
|\phantom{....................................................}|\phantom{............................................}|\phantom{.......}\\
\ce{CH3 - C - CH3 ->[Alc. KOH, \Delta][Dehydrohalogenation] \underset{2-Methyl-1-propene}{CH3 - C = CH2} ->[HBr, Peroxide] \underset{Isobutyl bromide}{CH3 - CH - CH2Br}}\\
|\phantom{.........................................................................................................}\\
\ce{\underset{tert-Butyl bromide}{Br}}\phantom{.......................................................................................................}
\end{array}\]
APPEARS IN
RELATED QUESTIONS
Draw the structure of the major monohalo product in the following reaction:
\[\ce{CH3CH2Br + NaI ->}\]
A hydrocarbon C5H10 does not react with chlorine in dark but gives a single monochloro compound C5H9Cl in bright sunlight. Identify the hydrocarbon.
Write the equation for the preparation of 1-iodobutane from 1-butanol.
Write the equation for the preparation of 1-iodobutane from 1-chlorobutane.
How will you bring about the following conversion?
Propene to 1-nitropropane
How will you bring about the following conversion?
Ethanol to ethyl fluoride
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2CH2Cl + NaI ->[acetone][heat]}\]
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2CH = CH2 + HBr->[peroxide]}\]
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH = C(CH3)2 + HBr ->}\]
How the following conversion can be carried out?
Benzyl alcohol to 2-phenylethanoic acid
How the following conversion can be carried out?
2-Methyl-1-propene to 2-chloro-2-methylpropane
How the following conversion can be carried out?
But-1-ene to n-butyliodide
Among the isomeric alkanes of molecular formula C5H12, identify the one that on photochemical chlorination yields four isomeric monochlorides.
3-Methyl-pent-2-ene of peroxide forms an addition product. The number of possible stereoisomers for the product is ______.
X and Y will be?
Alkyl halides are prepared from alcohols by treating with ______.
Which of the following alcohols will yield the corresponding alkyl chloride on reaction with concentrated HCl at room temperature?
The reagent used in the conversion of 1-butanol to 1-bromobutane is ______.
