Advertisements
Advertisements
Question
For the given cell, \[\ce{Mg | Mg^{2+} || Cu^{2+} | Cu}\]
(i) \[\ce{Mg}\] is cathode
(ii) \[\ce{Cu}\] is cathode
(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]
(iv) \[\ce{Cu}\] is the oxidising agent
Advertisements
Solution
(ii) \[\ce{Cu}\] is cathode
(iii) The cell reaction is \[\ce{Mg^+ Cu^{2+} -> Mg^{2+} + Cu}\]
Explanation:
(i) Left side of cell reaction represents oxidation half-cell i.e., oxidation of \[\ce{Mg}\] and right side of cell represents reduction half-cell reactions i.e., reduction of copper.
(ii) \[\ce{Cu}\] is reduced and reduction occurs at cathode.
(iii) \[\ce{Mg}\] is oxidized and oxidation occurs at anode.
(iv) Whole cell reaction can be written as
APPEARS IN
RELATED QUESTIONS
What happens if external potential applied becomes greater than E°cell of electrochemical cell?
Arrange the following metals in the order in which they displace each other from the solution of their salts.
\[\ce{Al, Cu, Fe, Mg}\] and \[\ce{Zn}\]
Construct a labelled diagram for the following cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`
Write cathode and anode reaction in a fuel cell.
A solution of CuSO4 is electrolysed using a current of 1.5 amperes for 10 minutes. What mass of Cu is deposited at cathode? [Atomic mass of Cu = 63.7]
A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and 40 seconds. The mass of Calcium in grams deposited at the cathode is (atomic mass of Ca is 40g/mol and 1F = 96500 C).
Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because ____________.
Cell equation: \[\ce{A + 2B^- -> A^{2+} + 2B}\]
\[\ce{A^{2+} + 2e^- -> A}\] E0 = +0.34 V and log10 k = 15.6 at 300 K for cell reactions find E0 for \[\ce{B^+ + e^- -> B}\]
Describe the electrolysis of molten NaCl using inert electrodes.
Two metals M1 and M2 have reduction potential values of −xV and +yV respectively. Which will liberate H2 and H2SO4.
`E_(cell)^Θ` = 1.1V for Daniel cell. Which of the following expressions are correct description of state of equilibrium in this cell?
(i) 1.1 = `K_c`
(ii) `(2.303RT)/(2F) logK_c` = 1.1
(iii) `log K_c = 2.2/0.059`
(iv) `log K_c` = 1.1
Match the terms given in Column I with the units given in Column II.
| Column I | Column II |
| (i) Λm | (a) S cm-¹ |
| (ii) ECell | (b) m-¹ |
| (iii) K | (c) S cm2 mol-¹ |
| (iv) G* | (d) V |
Match the terms given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Λm | (a) intensive property |
| (ii) ECell | (b) depends on number of ions/volume |
| (iii) K | (c) extensive property |
| (iv) ∆rGCell | (d) increases with dilution |
Assertion: ECell should have a positive value for the cell to function.
Reason: `"E"_("cathode") < "E"_("anode")`
Calculate the standard EMF ofa cell which involves the following cell reactions
\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]
Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.
In a Daniel cell, ______.
In a solution of CuSO4, how much time will be required to precipitate 2 g copper by 0.5 ampere current?
Galvanic cell is a device in which ______.
State the term for the following:
Two metal plates or wires through which the current enters and leaves the electrolytic cell.
