Advertisements
Advertisements
Question
Construct a labelled diagram for the following cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`
Advertisements
Solution
In the given representation of the cell, a standard Zn2+(1M)|Zn electrode is combined with standard hydrogen electrode to form the cell:
`Zn|Zn^(2+)(1M)||H^+(1M)|H_(2(g,1atm))|Pt`

APPEARS IN
RELATED QUESTIONS
What happens if external potential applied becomes greater than E°cell of electrochemical cell?
Can you store copper sulphate solutions in a zinc pot?
Write cathode and anode reaction in a fuel cell.
Define the following term:
Fuel cell
How many faradays of electricity are required to produce 6 g of Mg from MgCl2?
How many moles of electrons are required for reduction of 2 moles of Zn2+ to Zn?
For the electrochemical cell:
\[\ce{M | M+ || X- | X}\];
\[\ce{E^{\circ}_{{M^{+}/{M}}}}\] = 0.44 V,
\[\ce{E^{\circ}_{X/X^-}}\] = 0.33 V
Which of the following is TRUE for this data?
If 'I' stands for the distance between the electrodes and 'a' stands for the area of cross-section of the electrode, `"l"/"a"` refers to ____________.
A solution of CuSO4 is electrolysed using a current of 1.5 amperes for 10 minutes. What mass of Cu is deposited at cathode? [Atomic mass of Cu = 63.7]
What is the SI unit tor electrochemical equivalent?
A solution of Cu(NO3)2 is electrolyzed between platinum electrodes using 0.1 Faraday electricity. How many moles of Cu will be deposited at the cathode?
A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and 40 seconds. The mass of Calcium in grams deposited at the cathode is (atomic mass of Ca is 40g/mol and 1F = 96500 C).
Consider the change in the oxidation state of Bromine corresponding to different emf values as shown in the expression below:
\[\ce{BrO^-_4 ->[1.82 V] BrO^-_3 ->[1.5 V] HBrO ->[1.595 V] Br2 ->[1.0652 V] Br^-}\]
Then the species undergoing disproportionation is:
A certain current liberated 0.504 gm of hydrogen in 2 hours. How many grams of copper can be liberated by the same current flowing for the same time through copper sulphate solution.
Cell equation: \[\ce{A + 2B^- -> A^{2+} + 2B}\]
\[\ce{A^{2+} + 2e^- -> A}\] E0 = +0.34 V and log10 k = 15.6 at 300 K for cell reactions find E0 for \[\ce{B^+ + e^- -> B}\]
A gas X at 1 atm is bubbled through a solution containing a mixture of 1 MY− and 1 MZ− at 25°C. If the reduction potential of Z > Y > X, then ______.
Define cathode
Describe the construction of Daniel cell. Write the cell reaction.
Why is anode in galvanic cell considered to be negative and cathode positive electrode?
Can Fe3+ oxidises bromide to bromine under standard conditions?
Given: \[\ce{E^0_{{Fe^{3+}|Fe^{2+}}}}\] = 0.771 V
\[\ce{E^0_{{Br_{2}|Br^-}}}\] = −1.09 V
Is it possible to store copper sulphate in an iron vessel for a long time?
Given: \[\ce{E^0_{{Cu^{2+}|{Cu}}}}\] = 0.34 V and \[\ce{E^0_{{Fe^{2+}|{Fe}}}}\] = −0.44 V
A copper electrode is dipped in 0.1 M copper sulphate solution at 25°C. Calculate the electrode potential of copper.
[Given: \[\ce{E^0_{{Cu^{2+}|Cu}}}\] = 0.34 V]
For the cell \[\ce{Mg_{(s)}|Mg^{2+}_{( aq)}||Ag^+_{( aq)}|Ag_{(s)}}\], calculate the equilibrium constant at 25°C and maximum work that can be obtained during operation of cell.
Given: \[\ce{E^0_{{Mg^{2+}|Mg}}}\] = −2.37 V and \[\ce{E^0_{{Ag^{+}|Ag}}}\] = 0.80 V
Electrode potential for Mg electrode varies according to the equation
`E_(Mg^(2+) | Mg) = E_(Mg^(2+) | Mg)^Θ - 0.059/2 log 1/([Mg^(2+)])`. The graph of `E_(Mg^(2+) | Mg)` vs `log [Mg^(2+)]` is ______.
An electrochemical cell can behave like an electrolytic cell when ______.
Use the data given in below find out which option the order of reducing power is correct.
`"E"_("Cr"_2"O"_7^(2-)//"Cr"^(3+))^⊖`= 1.33 V `"E"_("Cl"_2//"Cl"^-)^⊖` = 1.36 V
`"E"_("MnO"_4^-//"Mn"^(2+))^⊖` = 1.51 V `"E"_("Cr"^(3+)//"Cr")^⊖` = - 0.74 V
Use the data given in below find out the most stable oxidised species.
`E^0 (Cr_2O_1^(2-))/(Cr_(3+))` = 1.33 V `E^0 (Cl_2)/(Cl^-)` = 1.36 V
`E^0 (MnO_4^-)/(MN^(2+))` = 1.51 V `E^0 (Cr^(3+))/(Cr)` = – 0.74 V
The quantity of charge required to obtain one mole of aluminium from Al2O3 is ______.
How will the pH of brine (aq. \[\ce{NaCl}\] solution) be affected when it is electrolysed?
Consider a cell given below:
\[\ce{Cu | Cu^{2+} || Cl^{-} | Cl_{2},Pt}\]
Write the reactions that occur at anode and cathode
Match the terms given in Column I with the units given in Column II.
| Column I | Column II |
| (i) Λm | (a) S cm-¹ |
| (ii) ECell | (b) m-¹ |
| (iii) K | (c) S cm2 mol-¹ |
| (iv) G* | (d) V |
Match the terms given in Column I with the items given in Column II.
| Column I | Column II |
| (i) Λm | (a) intensive property |
| (ii) ECell | (b) depends on number of ions/volume |
| (iii) K | (c) extensive property |
| (iv) ∆rGCell | (d) increases with dilution |
Assertion: ECell should have a positive value for the cell to function.
Reason: `"E"_("cathode") < "E"_("anode")`
The electrochemical cell stops working after some time because
Calculate the standard EMF ofa cell which involves the following cell reactions
\[\ce{Zn + 2 Ag+ -> Zn^{2+} + 2 Ag}\]
Given that \[\ce{E^{o}_{Zn/Zn^{2+}}}\] = 0.76 volt and \[\ce{E^{o}_{Ag/Ag^{+}}}\] = – 0.80 volt.
A current of 2.0 ampere passed for 5 hour through a molten salt deposits 22 g of the metal (Atomic mass = 177). The oxidation state of the metal in the metal salt is
If the half-cell reaction A + e– → A– has a large negative reduction potential, it follow that:-
In a Daniel cell, ______.
On which electrode the oxidation reaction takes place?
If the value of Ksp for Hg2Cl2 (s) is X then the value of X will be ____ where pX = - log X.
Given:
\[\ce{Hg2Cl2 + 2e- -> 2Hg(l) + 2Cl-}\], E° = 0.27 V
\[\ce{Hg+2 + 2e- -> 2Hg(l)}\] E° = 0.81 V
Which of the following is incorrect?
In a solution of CuSO4, how much time will be required to precipitate 2 g copper by 0.5 ampere current?
The number of moles of electrons passed when the current of 2 A is passed through a solution of electrolyte for 20 minutes is ______.
The two half cell reaction of an electrochemical cell is given as
\[\ce{Ag+ + e- -> Ag}\], `"E"_("Ag"^+//"Ag")^circ` = - 0.3995 V
\[\ce{Fe^{2+} -> Fe^{3+} + e-}\], `"E"_("Fe"^{3+}//"Fe")^{2+}` = - 0.7120 V
The value of EMF will be ______.
What should be the signs (positive/negative) for \[\ce{E^0_{cell}}\] and ΔG0 for a spontaneous redox reaction occurring under standard conditions?
Can we construct an electrochemical cell with two half-cells composed of ZnSO4 solution and zinc electrodes? Explain your answer.
The cell constant of a conductivity cell is 0.146 cm-1. What is the conductivity of 0.01 M solution of an electrolyte at 298 K, if the resistance of the cell is 1000 ohm?
Explain the types of electrochemical cells.
