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Question
Explain the following reaction with an example.
Esterification
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Solution
Substances having ester as the functional group are formed by a reaction between a carboxylic acid and an alcohol. This reaction is known as esterification.
E.g. When ethanoic acid is heated with ethanol in a water bath in the presence of an acid catalyst (concentrated sulphuric acid), ethyl ethanoate and water are formed.
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RELATED QUESTIONS
A student puts a drop of reaction mixture of a saponification reaction first a blue litmus paper and then on a red litmus paper. He may observe that:
(a) There is no change in the blue litmus paper and the red litmus paper turns white.
(b) There is no change in the red litmus paper and the blue litmus paper turns red.
(c) There is no change in the blue litmus paper and the red litmus paper turns blue.
(d) No change in colour is observed in both the litmus papers
What are esters ?
When you add a few drops of acetic acid to a test-tube containing sodium bicarbonate powder, which one of the following is your observation?
(A) No reaction takes place
(B) A colourless gas with pungent smell is released with brisk effervescence
(C) A brown coloured gas is released with brisk effervescence
(D) Formation of bubbles of a colourless and odourless gas
Choose the correct alternative and rewrite the following:
Acetic acid ..................
Draw the structure for the following compound.
Ethanoic acid
Which of the following will give brisk effervescence with sodium hydrogen carbonate and why?
CH3COOH, CH3CH2OH
What happens when ethanoic acid reacts with sodium carbonate? Write chemical equation of the reaction involved.
Vinegar is a solution of about:
(a) 5 to 8 per cent ethanoic acid in alcohol
(b) 5 to 8 per cent ethanoic acid in water
(c) 50 to 80 per cent ethanoic acid in water
(d) 50 to 80 per cent ethanoic acid in alcohol
An organic compound A (molecular formula C2H4O2) reacts with Na metal to form a compound B and evolves a gas which burns with a pop sound. Compound A on treatment with an alcohol C in the presence of a little of concentrated sulphuric acid forms a sweet-smelling compound D (molecular formula C3H6O2). Compound D on treatment with NaOH solution gives back B and C. Identify A, B, C and
Give the structural formulae of acetic acid.
If you are asked to report your observations about the following two properties of acetic acid, what would you report?
(i) Odour
(ii) Effect on litmus
A student is studying the properties of acetic acid. List two physical properties of acetic acid he observes. What happens when he adds a pinch of sodium hydrogen carbonate to this acid? Write any two observations.
Which one of the following are the correct observations about acetic acid?
(A) It turns blue litmus red and smells like vinegar
(B) It turns blue litmus red and smells like burning sulphur
(C) It turns res litmus blue and smells like vinegar
(D) It turns red litmus blue and has a fruity smell
On adding NaHCO3 to acetic acid, a gas is evolved which turns lime water milky due to the formation of:
(1) Calcium bicarbonate
(2) Calcium hydroxide
(3) Calcium carbonate
(4) Calcium acetate
Explain the following term with example.
Reduction
How will you carry out the following conversions?
Ethene to acetic acid
State how the following conversion can be carried out:
Ethyl chloride to Ethene.
When sodium hydrogen carbonate is added to ethanoic acid, a gas evolves. Consider the following statements about the gas evolved.
- It turns lime water milky.
- It is evolved with brisk effervescence.
- It has a smell of burning sulfur.
- It is also a by-product of respiration.
Name the oxidising agent used in the conversion of ethanol to ethanoic acid.
Write the chemical equation for the ethanol to ethanoic acid of an oxidation reaction.
