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Derive the relationship between half-life and decay constant of a radioelement. - Chemistry

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Question

Derive the relationship between half-life and decay constant of a radioelement.

Numerical
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Solution

Equation for the decay constant is given as,

`lambda = 2.303/"t" log_10  "N"_0/"N"`    ....(i)

Where, λ = Decay constant

N = Number of nuclei (atoms) present at time t

At t = 0, N = N0.

Hence, at t = t1/2, N = N0/2

Substitution of these values of N and t in equation (i) gives,

`lambda = 2.303/"t"_(1//2) log_10  "N"_0/("N"_0/2)`

`= 2.303/"t"_(1//2) log_10 2 = 2.303/"t"_(1//2) xx 0.3010 = 0.693/"t"_(1//2)`

Hence, `lambda = 0.693/"t"_(1//2) or "t"_(1//2) = 0.693/lambda`

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Chapter 13: Nuclear Chemistry and Radioactivity - Exercises [Page 202]

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Balbharati Chemistry [English] Standard 11 Maharashtra State Board
Chapter 13 Nuclear Chemistry and Radioactivity
Exercises | Q 3. (H) | Page 202

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