Advertisements
Advertisements
Questions
Derive the mathematical expression for law of radioactive decay for a sample of a radioactive nucleus
Deduce the expression, N = N0 e−λt, for the law of radioactive decay.
Derive the expression N = Noe-λt where symbols have their usual meanings
Advertisements
Solution
In any radioactive sample which undergoes α, β or γ-decay, it is found that the number of nuclei undergoing decay per unit time is proportional to the total number of nuclei in the sample.
If N is the number of nuclei in the sample and ΔN undergoes decay in time Δt, then we have
`(DeltaN)/(Deltat) propN`
`:.(DeltaN)/(Deltat)=lambdaN`
where λ is called the radioactive decay constant or disintegration constant.
The change in the number of nuclei in the sample is dN = −ΔN in time Δt, i.e. in the limit dt → 0. Thus, the rate of change of N is
`(dN)/dt= -lambdaN`
`:.(dN)/N = -lambdadt`
Now, integrating both the sides, we get
`int_(N_0)^N (dN)/N=-lambdaint_(t_0)^tdt`
∴ lnN - lnN0 = -λ(t-t0)
Here, N0 is the number of radioactive nuclei in the sample at some arbitrary time t0 and N is the number of radioactive nuclei at any subsequent time t. Setting t0 = 0 and rearranging, we get
`ln`
∴ N(t) = N0e-λt
This is the law of radioactive decay.
APPEARS IN
RELATED QUESTIONS
The decay constant of radioactive substance is 4.33 x 10-4 per year. Calculate its half life period.
(a) Write the basic nuclear process involved in the emission of β+ in a symbolic form, by a radioactive nucleus.
(b) In the reactions given below:
(i)`""_16^11C->_y^zB+x+v`
(ii)`""_6^12C+_6^12C->_a^20 Ne + _b^c He`
Find the values of x, y, and z and a, b and c.
Obtain the relation between the decay constant and half life of a radioactive sample.
Write symbolically the process expressing the β+ decay of `""_11^22Na`. Also write the basic nuclear process underlying this decay.
Obtain the amount of `""_27^60"Co"` necessary to provide a radioactive source of 8.0 mCi strength. The half-life of `""_27^60"Co"` is 5.3 years.
The half-life of `""_38^90 "Sr"` is 28 years. What is the disintegration rate of 15 mg of this isotope?
Under certain circumstances, a nucleus can decay by emitting a particle more massive than an α-particle. Consider the following decay processes:
\[\ce{^223_88Ra -> ^209_82Pb + ^14_6C}\]
\[\ce{^223_88 Ra -> ^219_86 Rn + ^4_2He}\]
Calculate the Q-values for these decays and determine that both are energetically allowed.
Represent Radioactive Decay curve using relation `N = N_o e^(-lambdat)` graphically
Using the equation `N = N_0e^(-lambdat)` obtain the relation between half-life (T) and decay constant (`lambda`) of a radioactive substance.
(a) Derive the relation between the decay constant and half life of a radioactive substance.
(b) A radioactive element reduces to 25% of its initial mass in 1000 years. Find its half life.
Why is it experimentally found difficult to detect neutrinos in this process ?
Define the activity of a given radioactive substance. Write its S.I. unit.
In a given sample, two radioisotopes, A and B, are initially present in the ration of 1 : 4. The half lives of A and B are respectively 100 years and 50 years. Find the time after which the amounts of A and B become equal.
A radioactive nucleus ‘A’ undergoes a series of decays according to the following scheme:

The mass number and atomic number of A are 180 and 72 respectively. What are these numbers for A4?
A freshly prepared radioactive source of half-life 2 h emits radiation of intensity which is 64 times the permissible safe level. The minimum time after which it would be possible to work safely with this source is
The masses of 11C and 11B are respectively 11.0114 u and 11.0093 u. Find the maximum energy a positron can have in the β*-decay of 11C to 11B.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
Calculate the maximum kinetic energy of the beta particle emitted in the following decay scheme:
12N → 12C* + e+ + v
12C* → 12C + γ (4.43MeV).
The atomic mass of 12N is 12.018613 u.
(Use Mass of proton mp = 1.007276 u, Mass of `""_1^1"H"` atom = 1.007825 u, Mass of neutron mn = 1.008665 u, Mass of electron = 0.0005486 u ≈ 511 keV/c2,1 u = 931 MeV/c2.)
The decay constant of 238U is 4.9 × 10−18 S−1. (a) What is the average-life of 238U? (b) What is the half-life of 238U? (c) By what factor does the activity of a 238U sample decrease in 9 × 109 years?
57Co decays to 57Fe by β+- emission. The resulting 57Fe is in its excited state and comes to the ground state by emitting γ-rays. The half-life of β+- decay is 270 days and that of the γ-emissions is 10−8 s. A sample of 57Co gives 5.0 × 109 gamma rays per second. How much time will elapse before the emission rate of gamma rays drops to 2.5 × 109per second?
A radioactive isotope is being produced at a constant rate dN/dt = R in an experiment. The isotope has a half-life t1/2. Show that after a time t >> t1/2 the number of active nuclei will become constant. Find the value of this constant.
Consider the situation of the previous problem. Suppose the production of the radioactive isotope starts at t = 0. Find the number of active nuclei at time t.
The half-life of 40K is 1.30 × 109 y. A sample of 1.00 g of pure KCI gives 160 counts s−1. Calculate the relative abundance of 40K (fraction of 40K present) in natural potassium.
Obtain a relation between the half-life of a radioactive substance and decay constant (λ).
Identify the nature of the radioactive radiations emitted in each step of the decay process given below.
`""_Z^A X -> _Z^A _-1^-4 Y ->_Z^A _-1^-4 W`
Define one Becquerel.
The isotope \[\ce{^57Co}\] decays by electron capture to \[\ce{^57Fe}\] with a half-life of 272 d. The \[\ce{^57Fe}\] nucleus is produced in an excited state, and it almost instantaneously emits gamma rays.
(a) Find the mean lifetime and decay constant for 57Co.
(b) If the activity of a radiation source 57Co is 2.0 µCi now, how many 57Co nuclei does the source contain?
c) What will be the activity after one year?
Before the year 1900 the activity per unit mass of atmospheric carbon due to the presence of 14C averaged about 0.255 Bq per gram of carbon.
(a) What fraction of carbon atoms were 14C?
(b) An archaeological specimen containing 500 mg of carbon, shows 174 decays in one hour. What is the age of the specimen, assuming that its activity per unit mass of carbon when the specimen died was equal to the average value of the air? The half-life of 14C is 5730 years.
Obtain an expression for the decay law of radioactivity. Hence show that the activity A(t) =λNO e-λt.
Which one of the following nuclei has shorter meant life?
Two radioactive materials Y1 and Y2 have decay constants '5`lambda`' and `lambda` respectively. Initially they have same number of nuclei. After time 't', the ratio of number of nuclei of Y1 to that of Y2 is `1/"e"`, then 't' is equal to ______.
What percentage of radioactive substance is left after five half-lives?
Two electrons are ejected in opposite directions from radioactive atoms in a sample of radioactive material. Let c denote the speed of light. Each electron has a speed of 0.67 c as measured by an observer in the laboratory. Their relative velocity is given by ______.
The half-life of a radioactive nuclide is 20 hrs. The fraction of the original activity that will remain after 40 hrs is ______.
If 10% of a radioactive material decay in 5 days, then the amount of original material left after 20 days is approximately :
The half-life of the radioactive substance is 40 days. The substance will disintegrate completely in
Suppose we consider a large number of containers each containing initially 10000 atoms of a radioactive material with a half life of 1 year. After 1 year ______.
When a nucleus in an atom undergoes a radioactive decay, the electronic energy levels of the atom ______.
Samples of two radioactive nuclides A and B are taken. λA and λB are the disintegration constants of A and B respectively. In which of the following cases, the two samples can simultaneously have the same decay rate at any time?
- Initial rate of decay of A is twice the initial rate of decay of B and λA = λB.
- Initial rate of decay of A is twice the initial rate of decay of B and λA > λB.
- Initial rate of decay of B is twice the initial rate of decay of A and λA > λB.
- Initial rate of decay of B is the same as the rate of decay of A at t = 2h and λB < λA.
The variation of decay rate of two radioactive samples A and B with time is shown in figure.

Which of the following statements are true?
- Decay constant of A is greater than that of B, hence A always decays faster than B.
- Decay constant of B is greater than that of A but its decay rate is always smaller than that of A.
- Decay constant of A is greater than that of B but it does not always decay faster than B.
- Decay constant of B is smaller than that of A but still its decay rate becomes equal to that of A at a later instant.
Draw a graph showing the variation of decay rate with number of active nuclei.
Which sample, A or B shown in figure has shorter mean-life?

A piece of wood from the ruins of an ancient building was found to have a 14C activity of 12 disintegrations per minute per gram of its carbon content. The 14C activity of the living wood is 16 disintegrations per minute per gram. How long ago did the tree, from which the wooden sample came, die? Given half-life of 14C is 5760 years.
Sometimes a radioactive nucleus decays into a nucleus which itself is radioactive. An example is :
\[\ce{^38Sulphur ->[half-life][= 2.48h] ^{38}Cl ->[half-life][= 0.62h] ^38Air (stable)}\]
Assume that we start with 1000 38S nuclei at time t = 0. The number of 38Cl is of count zero at t = 0 and will again be zero at t = ∞ . At what value of t, would the number of counts be a maximum?
The activity R of an unknown radioactive nuclide is measured at hourly intervals. The results found are tabulated as follows:
| t (h) | 0 | 1 | 2 | 3 | 4 |
| R (MBq) | 100 | 35.36 | 12.51 | 4.42 | 1.56 |
- Plot the graph of R versus t and calculate the half-life from the graph.
- Plot the graph of ln `(R/R_0)` versus t and obtain the value of half-life from the graph.
What is the half-life period of a radioactive material if its activity drops to 1/16th of its initial value of 30 years?
For the following reaction, the particle 'x' is 6C11 → 5B11 + β + X ______.
