English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Calculate the ‘spin only’ magnetic moment of M(aq)2+ ion (Z = 27). - Chemistry

Advertisements
Advertisements

Question

Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{ (aq)}}\] ion (Z = 27).

Numerical
Advertisements

Solution

The electronic configuration of the M atom (Z = 27) is [Ar] 3d7 4s2.

∴ Electronic configuration of M2+ = [Ar] 3d7

i.e., 

↑↓ ↑↓

So it has three unpaired electrons.

∴ 'Spin-only' magnetic moment is calculated by using formula,

(µ) = `sqrt("n"("n" + 2))` B.M.

= `sqrt(3(3 + 2))` B.M.

= `sqrt15` B.M.

= 3.87 B.M.

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: The d-block and f-block Elements - Intext Question [Page 103]

APPEARS IN

NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Intext Question | Q 4.8 | Page 103

RELATED QUESTIONS

Calculate magnetic moment of  `Fe_((aq))^(2+) ion (Z=26).`


In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?


Predict which of the following will be coloured in the aqueous solution?

Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.


How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]


When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.


Assertion (A): Cu cannot liberate hydrogen from acids.

Reason (R): Because it has positive electrode potential.


Answer the following question:

Which element of the first transition series has highest second ionisation enthalpy?


Mention any three processes where transition metals act as catalysts.


On the basis of the figure given below, answer the following questions:

  1. Why Manganese has lower melting point than Chromium?
  2. Why do transition metals of 3d series have lower melting points as compared to 4d series?
  3. In the third transition series, identify and name the metal with the highest melting point.

The element with atomic number 46 belongs to


Which of the following ions has the maximum magnetic moment?


Match List - I with List - II.

List - I List - II
(A) [Fe(CN)6]3− (i) 5.92 BM
(B) [Fe(H2O)6]3+ (ii) 0 BM
(C) [Fe(CN)6]4− (iii) 4.90 BM
(D) [Fe(H2O)6]2+ (iv) 1.73 BM

Choose the correct answer from the options given below.


The value of Δ0 for \[\ce{RhCl^{3-}6}\] is 243 KJ/mol which wavelength of light will promote an electron from. The colour of the complex is ______.


The given graph shows the trends in melting points of transition metals:

Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.


Consider the following standard electrode potential values:

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V

\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V

What is the cell potential for the redox reaction?


Account for the following:

Copper has an exceptionally positive `"E"_("M"^(2+)//"M")^0` value.


In order to protect iron from corrosion, which one will you prefer as a sacrificial electrode, Ni or Zn? Why? (Given standard electrode potentials of Ni, Fe and Zn are -0.25 V, -0.44 V and -0.76 V respectively.)


Account for the following:

Zirconium (Zr) and Hafnium (Hf) are difficult to separate.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×