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Answer the following in brief. Calculate the number of atoms in fcc unit cell. - Chemistry

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Question

Answer the following in brief.

Calculate the number of atoms in fcc unit cell.

Short/Brief Note
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Solution

  1. A face-centred cubic (fcc) unit cell has particles at the eight corners plus particles at the centre of its six faces.
  2. Each particle present at the corner of a given unit cell is shared with seven other neighbouring unit cells. As a result, its contribution to the given unit cell is only `1/8`.
    Thus, the number of particles present at corners per unit cell
    = 8 corner atoms `xx 1/8` atom per unit cell = 1
  3. Each particle at the centre of the six faces is shared with one neighbouring cube. Thus, 1/2 of each face particle belongs to the given unit cell.
    Thus, the number of particles present at faces per unit cell
    = 6 atoms at the faces `xx 1/2` atom per unit cell = 3
    Therefore, fcc unit cell has one corner particle plus 3 face particles, making total of 4 particles per unit cell.
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Chapter 1: Solid State - Exercises [Page 26]

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Balbharati Chemistry [English] Standard 12 Maharashtra State Board
Chapter 1 Solid State
Exercises | Q 3.03 | Page 26

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