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प्रश्न
Out of \[\ce{H2O}\] and \[\ce{H2S}\], which one has higher bond angle and why?
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उत्तर
Oxygen is more electronegative than sulphur, the bond angle of \[\ce{H2O}\] is greater, and the body pair electron of an \[\ce{OH}\] bond will be closer to oxygen, causing bond-pair bond-pair repulsion between bond pairs of two \[\ce{OH}\] bonds.
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संबंधित प्रश्न
a. Explain the trends in the following properties with reference to group 16:
1 Atomic radii and ionic radii
2 Density
3 ionisation enthalpy
4 Electronegativity
b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)
Give reasons: SO2 is reducing while TeO2 is an oxidising agent.
Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.
Why is H2O a liquid and H2S a gas?
The HNH angle value is higher than HPH, HAsH and HSbH angles. Why? [Hint: Can be explained on the basis of sp3 hybridisation in NH3 and only s−p bonding between hydrogen and other elements of the group].
Explain why inspite of nearly the same electronegativity, oxygen forms hydrogen bonding while chlorine does not.
Arrange the following in the order of property indicated for the given set:
F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.
Draw the structures of `H_3PO_2`
Arrange the following in the order of the property indicated against set :
H2O, H2S, H2Se, H2Te − increasing acidic character.
Give a reason for the following:
Fluorine gives only one oxide but chlorine gives a series of oxides.
The boiling points of hydrides of group 16 are in the order:
The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.
Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.
Which of the following statements are correct?
(i) \[\ce{CaF2 + H2SO4 -> CaSO4 + 2HF}\]
(ii) \[\ce{2HI + H2SO4 -> I2 + SO2 + 2H2O}\]
(iii) \[\ce{Cu + 2H2SO4 -> CuSO4 + SO2 + 2H2O}\]
(iv) \[\ce{Nacl + H2SO4 -> NaHSO4 + HCl}\]
In forming (i) \[\ce{N2 -> N^{+}2}\] and (ii) \[\ce{O2 -> O^{+}2}\]; the electrons respectively are removed from:
What is the basicity of \[\ce{H3PO4}\]?
______ is a gaseous element of group 16.
