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प्रश्न
Give reason to explain why ClF3 exists but FCl3 does not exist.
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उत्तर
Chlorine has vacant d-orbitals, which become excited upon bonding when electrons from the 3p-orbital are promoted to the 3d-orbital, giving it a covalency of three.
Due to the lack of unoccupied d-orbitals in the second energy shell, fluorine cannot expand its octet. As a result, it can only have one covalency.
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संबंधित प्रश्न
Iodine exists as
- polar molecular solid
- ionic solid
- nonpolar molecular solid
- hydrogen bonded molecular solid
Draw structure of Chlorine pentafluoride
Account for the following :
Acidic character increases from HF to HI.
Which halogen compound in the following pair will react faster in SN2 reaction CH3Br or CH3I.
Which halogen compound in each of the following pairs will react faster in SN2 reaction
(CH3)3 C – Cl or CH3 – Cl
Write two uses of ClO2.
With what neutral molecule is ClO− isoelectronic? Is that molecule a Lewis base?
Arrange the following in the order of property indicated for the given set:
HF, HCl, HBr, HI - increasing acid strength.
Complete chemical reactions are:Cl2 + H2O →
Select the correct alternative from the choices given :
The correct order of increasing acidic strength of the oxoacids of chlorine is:
Which one has the lowest boiling point?
Which is the strongest acid in the following:
Which of the following pairs of ions are isoelectronic and isostructural?
In solid state \[\ce{PCl5}\] is a ______.
The reaction \[\ce{3ClO- (aq) -> ClO3- (aq) + 2Cl- (aq) + 2Cl- (aq)}\] is an example of
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr, and HI decreases and so the acid strength increases.
In the light of the above statements, choose the correct answer from the options given below.
Write the name and formula of oxoacid of fluorine.
Arrange the following in the increasing order of the property mentioned:
MF, MCl, MBr, MI (ionic character)
