मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Arrange the following in the order of property indicated for the given set: HF, HCl, HBr, HI - increasing acid strength.

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प्रश्न

Arrange the following in the order of property indicated for the given set:

HF, HCl, HBr, HI - increasing acid strength.

Arrange the following according to the property mentioned against the given:

HF, HCI, HI, HBr in the order of increasing acid strength.

लघु उत्तर
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उत्तर १

HF < HCl < HBr < HI

The bond dissociation energy of the H-X molecules, where X=F, Cl, Br, and I, decreases with an increase in the atomic size. Since the H-I bond is the weakest, HI is the strongest acid.

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उत्तर २

The acid strength of HF, HCl, HBr and HI depends upon their bond dissociation enthalpies. Since the bond dissociation enthalpy of the H-X bond decreases from H-F to H-I as the size of the atom increases from F to I.
Thus, the acid strength order is HF < HCl < HBr < HI

The weak acidic strength of HF is also due to H-bonding, due to which the release of H+  becomes difficult.

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