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प्रश्न
Give reason to explain why ClF3 exists but FCl3 does not exist.
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उत्तर
Chlorine has vacant d-orbitals, which become excited upon bonding when electrons from the 3p-orbital are promoted to the 3d-orbital, giving it a covalency of three.
Due to the lack of unoccupied d-orbitals in the second energy shell, fluorine cannot expand its octet. As a result, it can only have one covalency.
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संबंधित प्रश्न
Iodine exists as
- polar molecular solid
- ionic solid
- nonpolar molecular solid
- hydrogen bonded molecular solid
Account for the following: Fluorine does not exhibit positive oxidation state.
Which halogen compound in each of the following pairs will react faster in SN2 reaction
(CH3)3 C – Cl or CH3 – Cl
Write two uses of ClO2.
Why are halogens coloured?
Write the reactions of F2 with water.
With what neutral molecule is ClO− isoelectronic? Is that molecule a Lewis base?
Arrange the following in the order of property indicated for the given set:
HF, HCl, HBr, HI - increasing acid strength.
Complete the following equations:
KMnO4 
Select the correct alternative from the choices given :
The correct order of increasing acidic strength of the oxoacids of chlorine is:
Cl2 acts as a bleaching agent.
Which one has the lowest boiling point?
Fluorine differs from the rest of the halogens in some of its properties. This is due to ____________.
In solid state \[\ce{PCl5}\] is a ______.
The reaction \[\ce{3ClO- (aq) -> ClO3- (aq) + 2Cl- (aq) + 2Cl- (aq)}\] is an example of
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr, and HI decreases and so the acid strength increases.
In the light of the above statements, choose the correct answer from the options given below.
Give a reason for the following:
Mn+2 compounds are more stable than Fe+2 compounds.
