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प्रश्न
Give reason to explain why ClF3 exists but FCl3 does not exist.
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उत्तर
Chlorine has vacant d-orbitals, which become excited upon bonding when electrons from the 3p-orbital are promoted to the 3d-orbital, giving it a covalency of three.
Due to the lack of unoccupied d-orbitals in the second energy shell, fluorine cannot expand its octet. As a result, it can only have one covalency.
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संबंधित प्रश्न
Fluorine is a stronger oxidising agent than chlorine. Why?
Compare the oxidizing action of F2 and Cl2 by considering parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy.
Account for the following :
Acidic character increases from HF to HI.
F2 has lower bond dissociation enthalpy than Cl2. Why?
Which halogen compound in the following pair will react faster in SN2 reaction CH3Br or CH3I.
Write the reactions of F2 with water.
Complete chemical reactions are:Cl2 + H2O →
Cl2 acts as a bleaching agent.
Which is the strongest acid in the following:
Which of the following pairs of ions are isoelectronic and isostructural?
Bond dissociation enthalpy of E–H (E = element) bonds is given below. Which of the compounds will act as the strongest reducing agent?
| Compound | \[\ce{NH3}\] | \[\ce{PH3}\] | \[\ce{AsH3}\] | \[\ce{SbH3}\] |
| Δdiss (E – H)/kJ mol–1 | 389 | 322 | 297 | 255 |
Which of the following is isoelectronic pair?
Solubility of iodine in water may be increase by adding
Iodine has lowest oxidiation state in ______.
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr, and HI decreases and so the acid strength increases.
In the light of the above statements, choose the correct answer from the options given below.
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr and HI decreases and so the acid strength increases.
In the light of the above statements, choose the correct answer from the options given below.
Give a reason for the following:
Mn+2 compounds are more stable than Fe+2 compounds.
