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प्रश्न
In solid state \[\ce{PCl5}\] is a ______.
विकल्प
covalent solid
octahedral structure
ionic solid with \[\ce{[PCl_{6}]^{+}}\] octahedral and \[\ce{[PCl_{4}]^{-} tetrahedra}\]
ionic solid with \[\ce{[PCl_{4}]^{+}}\] octahedral and \[\ce{[PCl_{6}]^{-} tetrahedra}\]
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उत्तर
In solid state \[\ce{PCl5}\] is a ionic solid with \[\ce{[PCl_{4}]^{+}}\] octahedral and \[\ce{[PCl_{6}]^{-} tetrahedra}\].
Explanation:


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संबंधित प्रश्न
Iodine exists as
- polar molecular solid
- ionic solid
- nonpolar molecular solid
- hydrogen bonded molecular solid
Account for the following: Fluorine does not exhibit positive oxidation state.
Fluorine is a stronger oxidising agent than chlorine. Why?
Account for the following :
Acidic character increases from HF to HI.
F2 has lower bond dissociation enthalpy than Cl2. Why?
Which halogen compound in each of the following pairs will react faster in SN2 reaction
(CH3)3 C – Cl or CH3 – Cl
Why are halogens coloured?
Write the reactions of F2 with water.
Cl2 acts as a bleaching agent.
Tincture of iodine is ____________.
Which is the strongest acid in the following:
Bond dissociation enthalpy of E–H (E = element) bonds is given below. Which of the compounds will act as the strongest reducing agent?
| Compound | \[\ce{NH3}\] | \[\ce{PH3}\] | \[\ce{AsH3}\] | \[\ce{SbH3}\] |
| Δdiss (E – H)/kJ mol–1 | 389 | 322 | 297 | 255 |
Reduction potentials of some ions are given below. Arrange them in decreasing order of oxidising power.
| Ion | \[\ce{CIO^{-}_{4}}\] | \[\ce{IO^{-}_{4}}\] | \[\ce{BrO^{-}_{4}}\] |
| Reduction potential EΘ/V |
EΘ = 1.19 V | EΘ = 1.65V | EΘ = 1.74 V |
Which of the following is isoelectronic pair?
Which of the following statements are true?
(i) Only type of interactions between particles of noble gases are due to weak dispersion forces.
(ii) Ionisation enthalpy of molecular oxygen is very close to that of xenon.
(iii) Hydrolysis of XeF6 is a redox reaction.
(iv) Xenon fluorides are not reactive.
Solubility of iodine in water may be increase by adding
Statement I: Acid strength increases in the order given as HF << HCl << HBr << HI.
Statement II: As the size of the elements F, Cl, Br, and I increase down the group, the bond strength of HF, HCl, HBr, and HI decreases and so the acid strength increases.
In the light of the above statements, choose the correct answer from the options given below.
